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Tetsu-to-Hagané
Vol. 55 (1969), No. 12

Tetsu-to-Hagané Vol. 55 (1969), No. 12

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ONLINE ISSN:	1883-2954
PRINT ISSN:	0021-1575
Publisher:	The Iron and Steel Institute of Japan

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09 Dec. (Last 30 Days)

Tetsu-to-Hagané Vol. 55 (1969), No. 12

随想

大谷正康

pp. 963-964

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Article Title

随想

Bibtex

Ris

Transfer of Silicon to Molten Iron by the Medium of SiO Gas

Tsuzuru NUIBE, Nobuo SANO, Yukio MATSUSHITA

pp. 965-980

Abstract

Chemical transport reactiOn of silicon from a sintered silicon carbide disc to Fe-C melt by SiO gas medium at 1450 to 1600°C was investigated in the view of kinetics.
The results were interpreted by a mass transport equatiOn derived from the mixed control theory, topochemical reactiOn theory and unreacted core model. Numerical values of all coefficients included in the equatiOn were experimentally determined as follows._??_
The most important factor for the silicon transfer by gaseous medium was found to be an activity of carbon in Fe-C melt. Therefore, the possibility of gaseous silicon absorptiOn into freely falling liquid'iron droplets in a blast furnace was concluded to depend upon the carbon content in droplets.
The derived general equatiOn is expected to be applicable to other conditiOns than experimentally undertaken.

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Transfer of Silicon to Molten Iron by the Medium of SiO Gas

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On Electro-slag Remelting of Steels

Kiichi NARITA, Toshio ONOYE, Katsutoshi IWAMOTO

pp. 981-1006

Abstract

Electro-slag remelting is one of the most suitable processes for the production of special steels.
In order to clarify the refining reactions of the process, carbon steels with further addition of various alloying elements and some commercial steels were remelted in a small scale furnace.
Further, to confirm the effect of electro-slag remelting on the mechanical properties of steels and to examine the industrialization of the process, stainless steels, low alloy steels, high speed steels and bearing steels were remelted in a large scale furnace. The results are as follows:
(1) Under same proper conditions, the remelted ingot shows a good skin condition and has homogeneous structures.
Moreover, the segregation, the size and amounts of the non-metallic inclusions are reduccd.
(2) Using CaF₂-based slags, even in the case of the electrode of 0 01% S, the desulphurization reaction is observed.
(3) In the mechanical properties of the electro-slag remelted steels, the ductility in the transverse direction increases noticeably, namely, the anisotropy reduces. For the high speed steel and the bearing steel, improvement of tool life and bearing life are respectively expected.
(4) The use of cast electrode and returned slag in the electro-slag remelting causes the cost down of the process.

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On Electro-slag Remelting of Steels

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Application of Oxygen Concentration Cells to Kinetic Study of Heterogeneous Reactions at Elevated Temperature

Kazuhiro GOTO, Minoru SASABE, Masahiro KAWAKAMI, Mayumi SOMENO, Yukio MATSUSHITA

pp. 1007-1029

Abstract

An oxygen concentration cell with zirconia and lime electrolyte has two characteristics in its performance at elevated temperature; First, the cell shows good reversibility against the change of oxygen pressure and temperature at the interface of the solid electrolyte and the electronic-conductor electrode. Second, the response time of the electromotive force is very short against the change of oxygen pressure and temperature.
The two characteristics have been applied to kinetic study of heterogeneous reactions at elevated temperature as follows:
(1) Gas composition profiles in the vicinity of the reaction surface have been continuously measured during the decarburization of liquid iron by carbon dioxide gas at 1550°C. It was shown that there is concentration gradient of carbon dioxide in the vicinity of the reaction surface and the gas phase is in unstable motion under the present experimental condition.
(2) Intraparticle gas composition of metal oxide powders has been continuously measured during the reduction by hydrogen gas and carbon monoxide gas. The change of the electromotive force demonstrated the step-wise change of the intraparticle gas composition in relation to the two intermediate phases equilibria.
(3) The rate of the change of oxygen pressure in the liquid metal and liquid oxide phases has been measured, when the oxygen pressure in the gas phase is quickly changed.
The micromechanism of the reactions under consideration was discussed from both results obtained by the electromotive force method and by other methods.

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Application of Oxygen Concentration Cells to Kinetic Study of Heterogeneous Reactions at Elevated Temperature

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Effects of Various Operating Conditions in LD Converter

Shigeo ASAI, Iwao MUCHI

pp. 1030-1040

Abstract

In order to predict the differences in process variables which would be caused by altering operating conditions, a part of the mathematical model of oxygen top blowing converter proposed previously has been modified, and on the basis of this modified model, numerical calculations have been conducted with the aid of digital computer (HITAC 5020E) for various operating conditions. The operating conditions considered to alter in this work are as follows:
1) feeding conditions of ore, lime and limestone, 2) back pressures of oxygen, 3) temperatures and carbon concentrations of pig iron charged into converter.

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Effects of Various Operating Conditions in LD Converter

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HCP Martensite in Iron Alloys

Zenji NISHIYAMA

pp. 1041-1050

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HCP Martensite in Iron Alloys

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Electron Fractography of Steels

Kimio KIMURA, Akira SAKAMOTO

pp. 1051-1070

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Electron Fractography of Steels

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討論会集録

三本木貢治, 近藤真一, 佐々木稔, 中沢孝夫, 渡辺正次郎, 吉永真弓, 福田充一郎, 国井和扶, 西田礼次郎, 小泉秀雄, 金本勝, 鴻巣彬, 中塚勝人, 下飯坂潤三, 松下幸雄, 松田亀松, 田中英夫, 前川静弥, 中川義隆, 福本勝, 谷口晃造, 浅野鋼一, 佐伯毅

pp. 1071-1086

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討論会集録

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抄録

pp. 1087-1102

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Tetsu-to-Hagané Vol. 55 (1969), No. 12

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Tetsu-to-Hagané Vol. 55 (1969), No. 12

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Application of Oxygen Concentration Cells to Kinetic Study of Heterogeneous Reactions at Elevated Temperature

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Effects of Various Operating Conditions in LD Converter

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HCP Martensite in Iron Alloys

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Electron Fractography of Steels

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討論会集録

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抄録

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Visualization of hydrogen and hydrogen-induced defects in tensile-deformed pure iron using hydrogen microprint and tritium autoradiography

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In-situ Observation of Sintering Interface between Al₂O₃ Particle / Single Crystalline Al₂O₃ Plate through Single Crystalline Al₂O₃ Plate