Steel Science Portal

Zairyo-to-Kankyo
New Arrival Alert : OFF

You can use this feature after you logged into the site.
Please click the button below.

Log in / Sign up
ONLINE ISSN: 1881-9664
PRINT ISSN: 0917-0480

Zairyo-to-Kankyo Vol. 69 (2020), No. 3

  • Energize

    Koji Fushimi

    pp. 63-63

    Bookmark

    You can use this feature after you logged into the site.
    Please click the button below.

    Log in / Sign Up

    DOI:10.3323/jcorr.69.63

  • Applicability of Electrical Equivalent Circuit Analysis Based on Voigt Model to Electrochemical Degradation Diagnosis of Heavy-duty Coating on Inner Surface of Oil-strage Tank and its Validation Using Depth Profile Analysis by IR and Raman Spectroscopy

    Koya Tokutake, Shinji Okazaki, Shohei Sasaki

    pp. 66-72

    Bookmark

    You can use this feature after you logged into the site.
    Please click the button below.

    Log in / Sign Up

    DOI:10.3323/jcorr.69.66

    Abstract

    To investigating the long-term degradation of a heavy-duty coating, Fourier transform infrared spectroscopy （FT-IR） and Raman spectroscopy along the depth direction of a vinyl ester resin organic coating containing glass flakes was conducted. The organic coating sample was applied to the inner surface of the bottom plate of the oil storage tank, and used for approximately seventeen years. In addition, the degradation evaluation using the electrical equivalent circuit （EEC） model considering depth direction distribution of R//C time-constant （Voigt measurement model） was examined in detail.In the FT-IR along the coating depth direction, no clear peak shift and/or disappearance of the spectrum was observed. On the other hand, the baseline of the Raman shift of the coating gradually increased from near the steel substrate interface toward coating surface. These results suggest that the long-term coating degradation appears as a difference in physical change along the depth direction, and supports the result that the impedance characteristics of the coating can be well-analyzed by Voigt measurement model. Furthermore, it is expected that the DC resistance value can be estimated accurately by the EEC analysis using Voigt measurement model.

  • Synchrotron XAFS Analysis of Corrosion on Steel Surface Using Materials Informatics

    Takahiro Ozawa, Shintaro Yamamoto, Takuya Mori, Mitsutoshi Yokomizo, Lei Li, Kazushi Yokoyama, Takumi Haruna

    pp. 73-76

    Bookmark

    You can use this feature after you logged into the site.
    Please click the button below.

    Log in / Sign Up

    DOI:10.3323/jcorr.69.73

    Abstract

    The rust layer changing behavior of initial corrosion on carbon steel was investigated by XAFS analysis using the large synchrotron radiation. Analysis of XANES spectrum and RDF by machine learning showed that the change in valence state and Fe-O covalent bond distance corresponded well with the initial corrosion rate. The distribution of valence and Fe-O bond distance of corrosion products on the steel surface showed a different tendency. These results suggest that the combination of synchrotron radiation analysis and machine learning is effective for elucidating rust formation mechanisms in initial corrosion.

    Recommended Articles: Analysis of Rust Layer Formed on Weathering Steel Exposed in Rural Area for 44Years [ View more ]

    x

    Readers Who Read This Article Also Read

    1. Analysis of Rust Layer Formed on Weathering Steel Exposed in Rural Area for 44Years Zairyo-to-Kankyo Vol.69(2020), No.3

  • Analysis of Rust Layer Formed on Weathering Steel Exposed in Rural Area for 44Years

    Hina Sato, Makoto Nagasawa, Michio Kaneko, Hiroshi Iki

    pp. 77-82

    Bookmark

    You can use this feature after you logged into the site.
    Please click the button below.

    Log in / Sign Up

    DOI:10.3323/jcorr.69.77

    Abstract

    Protective rust formed on Cr-Cu-Ni-P and Cr-Cu weathering steels （WSs） exposed for 44 years were analyzed to compare with previous studies for exposure test results for weathering steels. The formation of a typical protective rust composed of a polarizing layer （crystalline α-FeOOH and γ-FeOOH） and an insulation layer （fine α-FeOOH） was observed on both the weathering steels. Alloy elements were distributed in the protective rust layer. Cr enrichment was observed in the insulation layer. It was similar to previous studies and indicated that Cr contributed to form fine rust. Cu was present in the insulation layer, P was present in the insulation layer and the top of the polarizing layer, and Ni was present in the entire rust layer. Structure of the rust layers and the distribution of Cr and Ni were consistent in the results of previous studies, the exposure tests for less than 32 years, however there was a difference in the distribution of Cu and P.

    Recommended Articles: Synchrotron XAFS Analysis of Corrosion on Steel Surface Using Materials Informatics [ View more ]

    x

    Readers Who Read This Article Also Read

    1. Synchrotron XAFS Analysis of Corrosion on Steel Surface Using Materials Informatics Zairyo-to-Kankyo Vol.69(2020), No.3

  • Copper Tube Pitting Corrosion Product and Evaluation of Influence of Chloride Ion Concentration in Hot Water Environment

    Takeshi Daikuhara, Yasushiro Gomi, Naoto Nakazato, Masahiro Sakai

    pp. 83-89

    Bookmark

    You can use this feature after you logged into the site.
    Please click the button below.

    Log in / Sign Up

    DOI:10.3323/jcorr.69.83

    Abstract

    In order to clarify the corrosion resistance of copper tube in which 80℃ hot water flows, pitting production test by constant potential polarization was attempted and pitting potential was measured. In case of pre-coated specimen and under the condition that the test water was flowing, pitting corrosion occurred. And pitting potential was present between 190 mV vs.SSE and 210 mV vs.SSE, when the chloride ion concentration is 10 mg/L to 100 mg/L.
  • © 2020 Japan Society of Corrosion Engineering

Article Access Ranking

01 Mar. (Last 30 Days)

  1. Perspective toward Long-term Global Goal for Carbon Dioxide Mitigation in Steel Industry Tetsu-to-Hagané Vol.105(2019), No.6
  2. Recovery of Phosphorus from Modified Steelmaking Slag with High P2O5 Content via Leaching and Precipitation Tetsu-to-Hagané Vol.107(2021), No.2
  3. Effect of Varied Oxygen Levels on the Oxidation of a Magnetite Pellet Bed during Pot Furnace Induration ISIJ International Advance Publication
  4. Time-resolved and in-situ Observation of Semisolid Deformation in Al–Cu Alloys with Equiaxed and Columnar Grain Structures by Using a Combination Technique of 4D-CT and 3DXRD ISIJ International Advance Publication
  5. Improvement of Bragg-edge Neutron Transmission Imaging for Evaluating the Crystalline Phase Volume Fraction in Steel Composed of Ferrite and Austenite ISIJ International Advance Publication
  6. Deformation-induced Martensite Transformation Behavior during Tensile and Compressive Deformation in Low-alloy TRIP Steel Sheets ISIJ International Vol.61(2021), No.2
  7. Influence of Isothermal Treatment Prior to Initial Quenching of Q&P Process on Microstructure and Mechanical Properties of Medium Mn Steel ISIJ International Vol.61(2021), No.2
  8. Selective Separation of Metallic Fe Remaining in Slags Using Electrical Pulse Disintegration ISIJ International Advance Publication
  9. Effect of Initial Austenite Grain Size on Microstructure Development and Mechanical Properties in a Medium-carbon Steel Treated with One-step Quenching and Partitioning ISIJ International Vol.61(2021), No.2
  10. Spot-Welded Tensile Properties in Automobile Ultrahigh-Strength TRIP-Aided Martensitic Steel Sheet ISIJ International Vol.61(2021), No.2

Search Phrase Ranking

01 Mar. (Last 30 Days)

  1. blast furnace
  2. blast furnace permeability
  3. blast furnace coal tar injection
  4. blast furnace productivity
  5. 西山記念技術講座
  6. a practical approach to enhance wear resistance of bearings in molten zinc
  7. development of sanyo ultra refining process
  8. isij international
  9. spa-h
  10. weld distortion