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Japan Society of Corrosion Engineering

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Zairyo-to-Kankyo
Vol. 56 (2007), No. 8

Zairyo-to-Kankyo Vol. 56 (2007), No. 8

Corrosion Related Failure Analysis in Mechanical Design

Ryuichiro Ebara

pp. 341-342

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Corrosion Related Failure Analysis in Mechanical Design

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DOI:10.3323/jcorr.56.341
Mechanism of Hydrogen-related Failure I

Michihiko Nagumo

pp. 343-352

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Mechanism of Hydrogen-related Failure I

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DOI:10.3323/jcorr.56.343

Abstract

Major models so far proposed on the mechanism of hydrogen embrittlement are critically reviewed. The theories are classified into two streams, brittle or ductile fracture in nature. The theories for brittle fracture are triggering by internal pressure, surface energy reduction and lattice decohesion. The ductile fracture models presented here are hydrogen-assisted cracking, hydrogen-enhanced localized plasticity, adsorption-induced dislocation emission and autocatalytic effect on plastic instability. Interconnections of hydrogen embrittlement and stress corrosion cracking are also presented. Particular attention is paid on experimental conditions and assumptions on which the theories are based.
Recommended Articles: Mechanism of Hydrogen-related Failure II [ View more ]
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1. Mechanism of Hydrogen-related Failure II Zairyo-to-Kankyo Vol.56(2007), No.9
2. Function of Hydrogen in Embrittlement of High-strength Steels ISIJ International Vol.41(2001), No.6
A Case Study of Unusual Corrosion Damage in a Carbon Steel Pipe Wall Carrying Pure Water at Elevated Temperatures

Masanobu Matsumura

pp. 362-366

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A Case Study of Unusual Corrosion Damage in a Carbon Steel Pipe Wall Carrying Pure Water at Elevated Temperatures

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DOI:10.3323/jcorr.56.362

Abstract

The case cited here occurred in a waste heat boiler plant in 1993, which has many features in common with the case of Mihama nuclear power plant in 2004 in terms of piping materials, environmental conditions as well as in the location where the damage took place: very close to an upstream flow-meter. On this case, the cause was analyzed based on the best available knowledge and seemingly the best countermeasures for preventing a recurrence were taken. Seven years after the accident, in 2000, the effectiveness of these countermeasures was examined. The results of the examination and the newly obtained knowledge from the Mihama's case together confirmed the rationality of the opinion that the unusual thinning of pipe wall can be attributed not to the turbulence in fluid flow, but to a macro-cell corrosion.
Corrosion Tests of Noble Metals and Ti/IrO₂-Ta₂O₅ in Supercritical and Sub-critical Water Oxidation with Hydrochloric Acid

Taro Oe, Tomoyuki Iwamori, Noriyuki Anjo, Shinichiro Kawasaki, Akira Suzuki, Hiroyuki Daimon, Koichi Fujie

pp. 367-372

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Corrosion Tests of Noble Metals and Ti/IrO₂-Ta₂O₅ in Supercritical and Sub-critical Water Oxidation with Hydrochloric Acid

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DOI:10.3323/jcorr.56.367

Abstract

The corrosion resistance of noble metals and Ti/IrO₂-Ta₂O₅ in hydrochloric acid was evaluated to develop a material for a supercritical water oxidation reactor. The results of the corrosion tests in 20 wt% hydrochloric acid with the autoclaves showed Ir had good corrosion resistance between 300ºC and 600ºC. Although Ti-Pd showed active dissolution at 300ºC, the corrosion rate of Ir was less than 1.8 mm/y. This value was superior to that of Rh (26 mm/y) and Ru (14mm/y). The mass change of Ti/IrO₂-Ta₂O₅ was little. Ti/IrO₂-Ta₂O₅ has superior corrosion resistance to Ti-Pd. Using the continuous flow reactor for 893 h, the detachment of Ti/IrO₂-Ta₂O₅ coatings was observed at 550-580ºC. The detachment of coatings was not observed at 400-450ºC. At 550-580ºC, the thickness of oxide layer on Ti grew greater than 100 μm and the Vickers hardness of it was 660-772. High temperature and long time would cause the growth and brittle of oxide layer on Ti substrate. The study on the growth and the brittle of the oxide layer on Ti substrate is expected to use Ti/IrO₂-Ta₂O₅ at greater than 550ºC for a supercritical water oxidation reactor.

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Zairyo-to-Kankyo Vol. 56 (2007), No. 8

Corrosion Related Failure Analysis in Mechanical Design

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Mechanism of Hydrogen-related Failure I

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A Case Study of Unusual Corrosion Damage in a Carbon Steel Pipe Wall Carrying Pure Water at Elevated Temperatures

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Corrosion Tests of Noble Metals and Ti/IrO2-Ta2O5 in Supercritical and Sub-critical Water Oxidation with Hydrochloric Acid

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Corrosion Tests of Noble Metals and Ti/IrO₂-Ta₂O₅ in Supercritical and Sub-critical Water Oxidation with Hydrochloric Acid