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ONLINE ISSN: 1881-9664

PRINT ISSN: 0917-0480

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Japan Society of Corrosion Engineering

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Zairyo-to-Kankyo
Vol. 65 (2016), No. 9

Zairyo-to-Kankyo Vol. 65 (2016), No. 9

Expectations for Corrosion Science and Technology from the Viewpoint of Long-term Prediction

Naoki Taniguchi

pp. 363-364

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DOI:10.3323/jcorr.65.363
Corrosivity Difference among Alkanolamine Solutions Saturated with CO₂

Makoto Shimizu, Susumu Hirano, Yasuyoshi Tomoe

pp. 365-368

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Corrosivity Difference among Alkanolamine Solutions Saturated with CO₂

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DOI:10.3323/jcorr.65.365

Abstract

In the CO₂ separation and recovery process of CCS, high concentration alkanolamine (amine) solutions are widely used. However there exists a basic chemical structure difference between primary and tertiary amines. Therefore, corrosion tests were carried out on CO₂-saturated DGA (primary amine) and CO₂-saturated MDEA (tertiary amine). There was no distinct difference in corrosivity between DGA and MDEA at their low concentrations. However, remarkable difference was confirmed at their high concentrations. MDEA absorbs CO₂ as bicarbonate, whereas DGA absorbs CO₂ mainly as carbamate at high concentrations. It was concluded that DGA carbamate produces a stable water-soluble five-membered chelate ring with Fe²⁺, resulting in the high corrosivity. Carbamates, which do not produce a five-membered chelate ring with Fe²⁺ do not show very high corrosivity as DGA carbamate.
Corrosion Behavior of 13％Cr Steels in Supercritical CO₂ Environments

Shuji Hashizume

pp. 369-371

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Corrosion Behavior of 13％Cr Steels in Supercritical CO₂ Environments

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DOI:10.3323/jcorr.65.369

Abstract

In this paper, the effect of supercritical CO₂ on corrosion behavior of stainless steels, mainly 13%Cr steels, was reviewed. Corrosion rate of 13%Cr steels in supercritical CO₂ was similar to or less than that in gas CO₂. When the pressure of supercritical CO₂ became higher than 20MPa, pitting corrosion was more likely to occur in the steels. Under the supercritical CO₂ including 45kPa oxygen, crevice corrosion of 13%Cr steels was recognized. When oxygen partial pressure reduced to 4.5kPa in supercritical CO₂, no crevice corrosion was recognized in Steel B which was a low C steel with Mo addition. Steel B showed better corrosion resistance than Steel A which did not contain Mo, in all tested conditions, not only CO₂ gas conditions but also critical CO₂ conditions. Published papers related to effects of impurities such as NO₂, SO₂ and etc. on corrosion resistance of stainless steels and estimation of phase behavior of supercritical CO₂ were reviewed and summarized.
Recommended Articles: Demonstration of the Applicability of Nondestructive Microwave Testing to the Long-Range Inspection of Inner-Surface Cracks in Tubes [ View more ]
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CO₂ Injection Pump for CCS

Shigeru Yoshikawa, Ryotaro Yamamoto, Matsuho Miyasaka

pp. 372-377

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CO₂ Injection Pump for CCS

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DOI:10.3323/jcorr.65.372

Abstract

We outlined the notes on the structure and material selection of the CO₂ injection pump to be used in transport and injection in the CCS. The effect of CO₂ density changes in the inside of pump is taken into account in structural design. As CO₂ has a low viscosity, it is necessary to note selection and surface modification of the wearing parts. Since the increase in corrosion resistance becomes important if water or impurities are contained more than some level, it is necessary to pay attention to the selection of material used for the pump parts. We also introduce our supply experiences to the actual plants.
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1. Development and Penetration of Technologies for Preventing Corrosion of Electric Power Distribution Facilities Zairyo-to-Kankyo Vol.65(2016), No.12
2. Deformation Microstructure and Fracture Behavior in Creep-Exposed Alloy 617 MATERIALS TRANSACTIONS Vol.58(2017), No.3
3. Effect of Parametric Variations on the Local Compression Deformation of Aluminum Foam Sandwich Panels MATERIALS TRANSACTIONS Vol.58(2017), No.6
Corrosion Behavior of the Casing Steel Tube and the Cement Plug in the Abandoned Well in CCS

Masahiro Osada, Shigeki Azuma

pp. 378-382

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Corrosion Behavior of the Casing Steel Tube and the Cement Plug in the Abandoned Well in CCS

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DOI:10.3323/jcorr.65.378

Abstract

Regarding the geological storage of CO₂ in CCS, the stability of the casing steel tube and the cement plug in the abandoned well is important in order to investigate the potential for CO₂ leakage. Recent studies on chemical reaction (corrosion) of the casing steel and cement with stored CO₂ are introduced on the assumption that the CO₂ in the reservoir reaches the abandoned well.
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2. Demonstration of the Applicability of Nondestructive Microwave Testing to the Long-Range Inspection of Inner-Surface Cracks in Tubes MATERIALS TRANSACTIONS Vol.58(2017), No.4
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Similarity Analysis between Ōyuya Cast Iron Bathtub and Excavated Cast Iron Lump in the Precinct of Tōdaiji Temple

Mayumi Hori, Katsumi Shozugawa, Bokuichiro Takano, Motoyuki Matsuo

pp. 386-389

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Similarity Analysis between Ōyuya Cast Iron Bathtub and Excavated Cast Iron Lump in the Precinct of Tōdaiji Temple

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DOI:10.3323/jcorr.65.386

Abstract

In 2014, a cast iron lump was excavated from the precinct of Tōdaiji temple. We investigated the similarity of the excavated cast iron lump and cast iron bathtub in the Ōyuya (bath house), Tōdaiji temple. Cu concentration and the ratio of Cu/Fe were used to compare their similarity. On the basis of the Cu/Fe ratio, we have estimated that both cast iron materials have different compositions. Moreover, XRD analysis showed that the rust piece of the cast iron bathtub contained a considerable amount of β-FeOOH (Akaganeite), which is only formed in the presence of Cl^‒. β-FeOOH was also found in the metallic parts of the bathtub sample.
Fundamental Study on Anti-corrosive Method with Sacrificial Anode for Steel Members using Al-Zn Alloy Casting Plate and Fiber Sheet in Atmospheric Environment

Shigenobu Kainuma, Yohei Tsuchihashi, Shuji Ishihara, Daisuke Uchida, Akira Kaneko, Takao Yamauchi

pp. 390-397

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Fundamental Study on Anti-corrosive Method with Sacrificial Anode for Steel Members using Al-Zn Alloy Casting Plate and Fiber Sheet in Atmospheric Environment

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DOI:10.3323/jcorr.65.390

Abstract

Authors have developed anti-corrosive method using porous sintered Al-Zn plate and fiber sheet in atmospheric environment. In addition to this, reductive reaction mechanism of the corrosion product due to electrons supplied from the sacrificial anode was investigated. The purpose of this research is to clarify the validity of the anticorrosive method using the Al-Zn alloy casting plate instead of the porous sintered plate. Laboratory tests and atmospheric exposure tests in a corrosive environment by airborne sea salt were conducted on the model specimens with different Al-Zn alloy casting plates.

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