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Zairyo-to-Kankyo
Vol. 62 (2013), No. 4

Zairyo-to-Kankyo Vol. 62 (2013), No. 4

ONLINE ISSN:	1881-9664
PRINT ISSN:	0917-0480
Publisher:	Japan Society of Corrosion Engineering

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Zairyo-to-Kankyo Vol. 62 (2013), No. 4

Surface and Oxide Film of Metal

Sachiko Ono

pp. 133-

DOI:

10.3323/jcorr.62.133

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Article Title

Surface and Oxide Film of Metal

Bibtex

Ris

Effect of Trace Amounts of Salts on Properties of Passive Films Formed on SUS 304 Stainless Steel under Atmospheric Environment

Rock-Hoon Jung, Hiroaki Tsuchiya, Shinji Fujimoto

pp. 148-152

DOI:

10.3323/jcorr.62.148

Abstract

Passive films formed on SUS304 stainless steel that were covered with thin water layer containing various kinds of salt and exposed to atmospheric corrosion environment of 90％ relative humidity and 60℃ were characterized using X-ray photoelectron spectroscopy (XPS). Thickness and Cr content of passive films were affected by a minute amount of salts provided on the surface as a thin water layer. Thickness of the thin water layer on the surface of the steel seemed to be controlled by the equilibrium relative humidity of saturated solution of chlorides supplied on the specimen. Namely, the thickness of the thin water layer containing chloride with low equilibrium relative humidity was larger compared to that containing the chloride with higher equilibrium relative humidity. As a result, the selective dissolution of Fe is stimulated under the thicker water layer to be the more Cr containing passive films. Chlorides enhanced the formation of more Cr enriched passive films, but more concentrated chloride caused localized corrosion. In particular, passive films formed with the thin water layer containing suitable amount of sodium chloride occasionally exhibited high localized corrosion resistance. Sulfates also accelerated the selective dissolution of Fe and increased Cr content in passive films, resulting in stable growth of passive film without localized corrosion.

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Article Title

Effect of Trace Amounts of Salts on Properties of Passive Films Formed on SUS 304 Stainless Steel under Atmospheric Environment

Bibtex

Ris

鉄筋表面の環境改善を考慮したコンクリート中鉄筋のカソード防食設計

Hiroyuki Kobayashi, Yoshikazu Akira, Toru Yamaji, Hidenori Hamada, Toru Wakabayashi, Noriyasu Mochizuki

pp. 153-160

DOI:

10.3323/jcorr.62.153

Abstract

We investigated a cathodic protection design basis for reinforced concrete structures exposed to atmospheric conditions. If such structures in severely corrosive environments do not satisfy the relevant cathodic protection criteria, the situation can be remedied by supplying more current than the design value. However, as such energization results in rapid consumption of the water surrounding the anode, the voltage DC power supply may rise. Using electrochemical measurement and numerical simulation, we sought to clarify the effects resulting from environmental improvement of rebar surfaces using cathodic protection and devised a new design method. Then, via cathodic protection examination using concrete specimens affected by rebar corrosion, the validity of the new design method was determined. The approach was found to be suitable for economical and stable cathodic protection.

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Article Title

鉄筋表面の環境改善を考慮したコンクリート中鉄筋のカソード防食設計

Bibtex

Ris

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MATERIALS TRANSACTIONS Vol.54(2013), No.6
Chemical State Evolution of Iron Ore Sinter Investigated by Wide-Area Imaging XAFS

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Zairyo-to-Kankyo Vol. 62 (2013), No. 4

Keyword Ranking

blast furnace

ferrocoke

high-strength steel alloys

isij international

slag/metal reactions in steelmaking

tramp elements

trip steel martensitic transformation

bend

continuous casting slab

crystallization

Zairyo-to-Kankyo Vol. 62 (2013), No. 4

Surface and Oxide Film of Metal

Share it with SNS

Effect of Trace Amounts of Salts on Properties of Passive Films Formed on SUS 304 Stainless Steel under Atmospheric Environment

Share it with SNS

鉄筋表面の環境改善を考慮したコンクリート中鉄筋のカソード防食設計

Share it with SNS

Article Access Ranking

Wettability of CaS Against Molten Iron at 1873 K

Perspectives on the Promising Pathways to Zero Carbon Emissions in the Steel Industry toward 2050

Analysis of Peritectic Solidification of Ag–Sn Alloys by Unidirectional Solidification Experiment

Thermodynamic Calculation of Grain Boundary Composition in Ferritic Steels and Its Application for Controlling the Hall–Petch Coefficient

Effects of interface anisotropy on the solidification morphology of zinc alloys and development of data assimilation for their estimation

Hydrogen-induced vacancy formation process in austenitic stainless steel 304

Microstructural Analysis of Reduced Multicomponent Calcium Ferrite Using STEM-EDS and 3DAP

PREFACE

Chemical State Evolution of Iron Ore Sinter Investigated by Wide-Area Imaging XAFS

Bend Failure Mechanism of Zinc Coated Advanced High Strength Steel

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