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鉄と鋼
Vol. 71 (1985), No. 1

鉄と鋼 Vol. 71 (1985), No. 1

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オンライン版ISSN:	1883-2954
冊子版ISSN:	0021-1575
発行機関:	The Iron and Steel Institute of Japan

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キーワードランキング

21 Nov. (Last 30 Days)

鉄と鋼 Vol. 71 (1985), No. 1

Recent Trend of Squeeze Casting

Manabu KIUCHI

pp. 12-18

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New Technology of Iron Ore Mining

Nobunao NISHIDA

pp. 19-26

抄録

[in Japanese]

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Shearing Techniques and Their Resulting Sheared Surfaces

Masao MURAKAWA

pp. 27-33

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Influence of Hot Metal Flow on the Heat Transfer in a Blast Furnace Hearth

Jiro OHNO, Masaharu TACHIMORI, Masakazu NAKAMURA, Yukiaki HARA

pp. 34-40

抄録

The influence of hot metal flow on the heat transfer in a blast furnace hearth was studied by the flow calculation, the water model experiment and the investigation of wear profiles of dissected hearth.
The hearth flow can be classified into the one in a uniformly packed hearth of coke with good permeability and the one in a hearth having a coke free space at the bottom part of it. The result of water model experiment shows that the heat transfer of the former is similar to that of the cyrindrical packed bed, and that of the latter the laminar flow within parallel plates.
By virtue of these similarities, the heat conductance of a packed hearth can be expressed as the function of the dimension of hearth, the flow rate as well as the thermal properties of fluid. The heat conductance of real furnaces can be shown as
h=(14.2/d)+(6.3/D+1.7/d²)(Q/D),
where h is the heat conductance (kcal/m² h°C), d is the depth of iron pool (m), D is the diameter of hearth (m) and Q is the tapping rate (t/h).
The wear level at the bottom part of carbon hearth can be calculated from h thus obtained. Good agreement has been confirmed between the calculated wear level and the observed ones at dissected hearths.

他の人はこちらも検索

Report of the Refractory Committee of the Joint Research Society of ISIJ

鉄と鋼 Vol.62(1976), No.14

Estimation of Refractory Wear and Solidified Layer Distribution in the Blast Furnace Hearth and Its Application to the Operation

鉄と鋼 Vol.73(1987), No.15

Development of a Stave Cooler with High Stability of Blast Furnace's Working Profile and without Brick Laying Work

鉄と鋼 Vol.78(1992), No.7

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Burden Distribution in Shaft Furnace for Direct Reduction of Iron Ores

Shoichi KUME, Kunio HACHISUKA, Takashi SUGIYAMA, Toru WAKABAYASHI, Rikuo KAHARU, Yoshisato SUGA

pp. 41-46

抄録

Experiment was conducted with a 45°segment full-scale model to investigate the burden distribution in direct reduction shaft furnaces equipped with the charging pipe. The findings are as follows :
1) The charged material moves from the charging pipe first in a pushing flow like a landslide and then in a rolling flow toward the wall.
2) Size segregation occurs in the rolling flow through a percolation process, while less segregation in the pushing flow.
3) The size distribution can be expressed as relative distance of charged material movement irrespective of throat diameter.
4) High content of fine particle in lump ore layer remarkably increases the gas permeability resistance around the charging pipe.

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Dimensionless Groups on a Countercurrent Reduction of Iron Ore

鉄と鋼 Vol.61(1975), No.7

Production of direct reduced iron by a sheet material inserting metallization method

ISIJ International Vol.41(2001), No.Suppl

Countercurrent Reduction of Iron Ore Particles by Fluidized Rotary Bed with Drum Type Reactors

鉄と鋼 Vol.72(1986), No.7

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A Simulation Model for Gas Flow in Direct Reduction Furnace for Iron Ores

Shoichi KUME, Takashi SUGIYAMA, Yasuto SHIMOMURA, Yoshisato SUGA, Kunio HACHISUKA, Tooru WAKABAYASHI

pp. 47-54

抄録

Based on the previous research on the blast furnace simulation, a gas flow simulation model for direct reduction shaft furnaces which are free of a coke layer and operated by a fixed charging cylinder system was developed. In order to derive the calculation formula, experiments were conducted using a burden distribution model for the fixed charging cylinder system mentioned above to analyze the characteristic features of the furnace. Radial distributions of particle diameter and void fraction were considered for the estimation of gas velocity distribution in this model. The results obtained by this simulation system agreed well with those acquired in actual operation of a 500 t/d furnace.

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Solubility and Dissolution Rate of Water Vapor in Liquid CaO-SiO₂-Al₂O₃ Slags

Shiro BAN-YA, Yasutaka IGUCHI, Shunsuke NAGATA

pp. 55-62

抄録

The solubility of water vapor and the rate of water vapor dissolution in liquid CaO-SiO₂-Al₂O₃ slags have been measured at 1 400°C by a sampling method.
From the results obtained, solubilities of water in slags were shown with water-vapor capacity, defined by K' =(%H₂O)_s/√P_H₂O.
The apparent rate of water vapor dissolution was independent of the flow rate of Ar-H₂O gas mixture over the range of 200910 ml/min. The dissolved water content was a linear function of the square root of time during the initial period of dissolution with a slope proportional to the square root of P_H₂O in the gas.
Consequently, the reaction would be controlled by the non-steady-state diffusion of H₂O in the bulk slag. The obtained apparent diffusion coefficient of water vapor, D_H₂O, in 44 mol% CaO-44 mol%SiO₂-12 mol%Al₂O₃ slag at 1 400°C was 1.9×10^-5 cm²/s. The effects of slag composition, such as alumina content or basicity and temperature on D_H₂O were discussed.

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Rate of Dephosphorization of Liquid Iron by the Flux of Na₂O-SiO₂ System

Kyoji KUNISADA, Hikoya IWAI

pp. 63-69

抄録

The experiments of the dephosphorization of liquid iron by Na₂O-SiO₂ flux containing Fe₂O₃ were carried out at temperatures of 1 550, 1 600 and 1 650°C, and kinetics of the reaction was studied.
The distribution ratio of phosphorus obtained from the experiments was expressed as follow :
log L_P=log (%P)/[%P]=0.092(%Na₂O)+2.5 log(%Fe_tO)-3.79 (1 600°C)
The rate of dephosphorization was analysed on the assumption that the reaction was first order, and the reaction rate constant obtained was 0.12-2.40 ×10^-2 cm/s. The apparent activation energy of the reaction obtained was 13-34 kcal/mol. The reaction rate constant showed a strong correlation with the distribution ratio of phosphorus obtained from the experiment.
The diffusion of phosphorus from slag-liquid iron interface to slag phase was considered as the ratedetermining step in the dephosphorization reaction.

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Phosphorus Distribution between CaO-CaF₂-SiO₂ Melts Saturated with Solid CaO Compounds and Carbon-saturated Iron

鉄と鋼 Vol.71(1985), No.6

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Rate of Absorption of Injected Nitrogen in Molten Iron

Korehito KADOGUCHI, Masamichi SANO, Kazumi MORI

pp. 70-77

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A study was made on the rate of absorption of injected nitrogen in molten iron. Nitrogen was injected into the melt through an immersed alumina nozzle of 0.1 cm in I. D. and 0.3 cm in O. D. The immersion depth of the nozzle was 3.34.7 cm. The gas flow rate was 1.121.67 Ncm³/s. The oxygen and sulfur concentrations in the melt were varied widely. During the nitrogen absorption experiment, the bubble formation time was measured by using a pressure pulse technique.
The measured rate data are compared with calculations from a mixed control model of liquid-phase mass transfer and chemical reaction at the bubble-metal interface. Nitrogen absorption during bubble formation is taken into account in the model. From the comparison between calculation and experiment, the chemical reaction rate constant is obtained. It is shown that the chemical reaction rate constant decreases with increasing [%O]+[%S]/2. The rate constant for the bubble interface roughly agrees with that for the free surface of melt.

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Prediction of the Formation Region of Eutectic NbC in a Large 12Cr-Mo-V-Nb Steel Ingot

Kimihiko AKAHORI, Shigeo MAENO, Hideyo KODAMA, Norio MORISADA, Toshihiko OSHIMA

pp. 78-84

抄録

The purpose of this study is to predict the formation region of eutectic NbC in large ingots and to eliminate its detrimental effects. The correlation between the formation region of eutectic NbC and the ratio of the height H to the diameter D (H/D) was investigated experimentally using ingots of 2 t and 10 t and the temperature gradient at the end of solidification in these ingots was calculated by a finite difference method.
The plots of the logarithm of the critical temperature gradient for the formation of eutectic NbC which was obtained experimentally against the logarithm of the calculated average cooling rate during solidification yielded a straight line. It was predicted from this result that when casting a 100 t ingot eutectic NbC would not be formed if the value of H/D is less than 0.6 and magnetic particle test indication would not be detected if the value of H/D is less than 1.0. A 100 t ingot having ratio H/D of 0.96 was made and a turbine rotor shaft was produced from this ingot. The center core portion of the rotor shaft had satisfactory mechanical properties and no indication of defects was detected by magnetic particle testing.

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The Effect of Tensile Strength and Ductility on High Temperature Low Cycle Fatigue of Cast Ni-base Superalloys

Hidehiro ONODERA, Yoshihito RO, Toshihiro YAMAGATA, Michio YAMAZAKI

pp. 85-91

抄録

The effect of tensile strength and ductility on high temperature low cycle fatigue of cast Ni-base superalloys was studied. The main results obtained are as follows :
(1) At total strain ranges above 0.01, where plastic fatigue was dominant, fatigue lives of high ductility alloys (MM247 as cast and HT, IN738LC as cast, TM-321 HT, HT standing for heat-treated) were longer than those of low ductility alloys (TM-185 as cast, TM-49 as cast). At total strain ranges below 0.005, where elastic fatigue was dominant, fatigue lives of high strength alloys (TM-185 as cast, TM-321 as cast and HT, MM247 as cast and HT) were longer than those of low strength alloy (IN738LC as cast).
(2) High temperature low cycle fatigue lives of cast Ni-base superalloys could be roughly estimated by the Universal Slope method combined with 10% rule.
(3) Fatigue crack was considered to initiate at the surface-connected grain boundary, and crack propagation was mixture of intergranular and transgranular types.
(4) In the long life range, preferential oxidation of surface-connected grain boundaries was considered to reduce fatigue life.

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The Role of Simulated HTGR Helium on the Low Cycle Fatigue Behavior of Ni-Cr-W Alloys

Kazuo FURUYA, Kouichi SATO, Toshio KAINUMA, Heitarou YOSHIDA

pp. 92-99

抄録

Low cycle fatigue behavior of two Ni-Cr-W alloys (Ni-15Cr-25W (KSN) and Ni-23Cr-18W (113MA)) was investigated at 1 273 K in the simulated High Temperature Gas-cooled Reactor (HTGR) helium, He-2. Both alloys showed little cyclic hardening in fatigue tests and failed in a completely intergranular manner. Although the fatigue life (N_f) of 113MA was a little longer than that of KSN, observed intergranular fractures indicated that the fatigue properties of both alloys were severely influenced by impurities in He-2.
As well as in He-2, fatigue tests of KSN and 113MA were carried out in pure He, air and vacuum. The results clearly showed that, regardless of the concentration of reactive gases, both alloys failed intergranularly with short N_fs in gaseous environments, as compared with the transgranular fracture with long N_f in vacuum. A minor effect of impurity contents was shown as an increase in N_f with substituting the environment from air then He-2 to pure He. It is considered from these behaviors that the fatigue fractures were affected by residual oxygen gas in the environments penetrating into specimens along the grain boundaries.

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Properties of Induction Heat-treated High Strength Spring Wire

Kazuhiro KAWASAKI, Yoshiki SETO, Takao YAMAZAKI

pp. 100-106

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Induction heat-treatment technique has been applied to develop a new high strength Si-Cr steel (SAE 9254) spring wire. The features of this technique are : (1) uniform heating (by rapid heating and holding) and (2) short heating time.
The induction-heating, quenched and tempered wires (ITW) with diameter of 12 mm show fine micro structure, fine austenite grains and less decarburization. The ITW have very high tensile strength from 1 770 to 2 060 MPa, and also show high ductility and toughness. These properties are attributed to their fine microstructure and non-equilibrium tempering effect with short induction heating time for tempering, and provide excellent cold formability.
Coil springs cold-coiled from the ITW possess sufficient sag resistance and fatigue life. As no decrease in fatigue life is observed even at such high strengths, advantage can be taken of the fact that sag resistance rises with the increase in tensile strength. Since maximum stress of coil spring can be raised by using the ITW, considerable weight saving becomes possible.

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Effect of Induction Heating Tempering for Strengthening and Toughening of Spring Steel

鉄と鋼 Vol.74(1988), No.2

Reduction of Delayed Fracture Susceptibility of Tempered Martensitic Steel through Increased Si Content and Surface Softening

ISIJ International Vol.53(2013), No.4

An Approach to Predict the Depth of the Decarburized Ferrite Layer of Spring Steel Based on Measured Temperature History of Material during Cooling

ISIJ International Vol.54(2014), No.7

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Effects of Alloying Elements on Embrittlement of 15Cr-26Ni-1.25Mo Type Precipitation Hardening Alloy

Katsumi IIJIMA, Norio YAMADA, Seishin KIRIHARA

pp. 107-113

抄録

The object of this study is to characterize the effect of alloying elements on the toughness of 15Cr-26Ni-1.25Mo type alloy steels (A286) aged at 650°C.
The results obtained are summerized as follows.
(1) The Charpy absorbed energy of 15Cr-26Ni-1.25Mo type alloy steels aged at 650°C was decreased with increasing C content. This fact suggestes that aging embrittlement closely depended on C content.
(2) Precipitates were found on the grain-boundaries of the alloys aged at 650°C for 1 500h. Microscopic examination indicated that these precipitates grew as aging time increased. Auger electron spectroscopy showed that titanium carbides were included in the precipitates.
(3) Decreases of C to 0.03wt% and Ti to 1.65wt% were beneficial in keeping good Charpy absorbed energy the value of 35 to 55 N-m in the specimens aged for 6 000h at 650°C, without reduction of creep rupture strength at 650°C.

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Mechanism of High Temperature Oxidation of Austenitic Stainless Steels with High Silicon

鉄と鋼 Vol.67(1981), No.1

Production of Ferro-nickel-Current State of the Industry and Production Technology

鉄と鋼 Vol.71(1985), No.2

Grain Refinement of Ferrite-pearlite Structure of Low Carbon Steel through the Controlled Rolling Process

鉄と鋼 Vol.70(1984), No.3

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Creep Fracture Mechanism Maps Based on Creep Rupture Tests up to about 100 000 h for Type 316 Stainless Steel

Norio SHINYA, Hideo TANAKA, Masaharu MURATA, Masatsugu KAISE, Shin YOKOI

pp. 114-120

抄録

Specimens of Type 316 stainless steel with rupture periods up to about 100 000h have been examined. metallographically in order to clarify creep fracture mechanisms and effects of microstructure on the mechanisms.
Main results obtained are as follows.
(1) Creep fracture mechanism maps constructed experimentally show the fields of dominance of each fracture mechanism : transgranular creep fracture, wedge-type cracking at triple point, intergranular cavitation, and cracking at interface between intermetallic phases and austenite matrix. The maps also indicate that this steel in power plants is used within the field of the cracking due to the intermetallic phases of sigma and chi.
(2) The creep fracture mechanisms are subject to the influence of precipitation behavior at grain boundary: grain boundary M₂₃C₆ promotes the transition from the wedge-type cracking to the intergranular cavitation, and grain boundary sigma or chi phases lead to the grain boundary cracking.
(3) Higher aluminum content than about 0.03% leads to the precipitation of AlN associated with the grain boundary sigma or chi phases, and this AlN is thought to cause early formation of the grain boundary cracks, resulting in the marked reductions in rupture strength and ductility at longer time.

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Hot Deformation of Austenitic Stainless Steel Type 316 up to Strain Rates of 100s^-1

ISIJ International Vol.45(2005), No.2

Production of Ferro-nickel-Current State of the Industry and Production Technology

鉄と鋼 Vol.71(1985), No.2

日本鉄鋼協会第107回講演大会講演概要集(II) その1

鉄と鋼 Vol.70(1984), No.5

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Service Life Prediction of Industrial Pipe-line

Kazuo YAMAMOTO, Shigeru MIZOGUTI, Shinichiro NAGANO, Kunimasa YOSHIMITU, Etsuo NOMURA

pp. 121-126

抄録

To perform the water-leak protection and effective renewal of industrial pipe line, the life-time prediction has been discussed on the basis of the measurements of the wall thickness of pipes in service. The followings are concluded : (1) the life time of a pipe line in inside corrosion can be predicted from the maximum pitting depth estimated by the extreme value statistical analysis of the data obtained from the relation between corrosion pit depth and rust-lump height. (2) the grooving depth of ERW pipes can be measured by the ultrasonic angle beam testing method quantitatively. If the supply water is drained, the estimation of the grooving depth is qualitatively made by means of the X-ray transmission method.

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R & D and A & C

鉄と鋼 Vol.77(1991), No.1

Carbide Capacity of CaO-SiO₂-CaF₂(-Na₂O) Slags at 1 773 K

ISIJ International Vol.44(2004), No.2

Viscosity, Surface Tension, and Density of Blast Furnace Slag and Synthetic Slags at Manufacturing Condition of Hard Granulated Slag

鉄と鋼 Vol.67(1981), No.9

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Solidification Behavior of a Nickel-base Superalloy, IN-100

Yoshinori MURATA, Natsuo YUKAWA, Toshiharu NODA, Takashi MITANI

pp. 127-134

抄録

Solidification behavior of IN-100 and effect of alloying elements on it were investigated by means of differential thermal analysis (DTA), microstructural observation, X-ray diffraction, and EPMA analysis.
In alloy IN-100, it was revealed that six phase reactions took place successively during cooling from melt. These reactions and the onset temperatures were as follows, 1) L→γ(1 329°C), 2) L→γ+MC(D) (1319°C), 3) L→γ+MC(ID) (1 310°C), 4) L→γ+γ' (1 259°C), 5)γγ'→(1 210°C), and 6) L→γ+M₃B₂ (1 200°C), where L is melt, γ is fcc phase. MC(D) and MC(ID) denote MC carbides formed among dendrite arms and interdendritic regions, respectively. γ' is Ll₂ type ordered phase and M₃B₂ denotes boride phase.
The occurrence of two kinds of carbide reactions ((2) and (3)) and M₃B₂ eutectic reaction ((6)) was identified for the first time in this study. SEM observation on the carbides, which were embossed on the γ matrix by an electrolytic etching, showed that the carbides had three types of morphology. These were blocky, lattice-like and flaky in shape. It was found that the blocky carbides were contained in MC(D), while the lattice-like and flaky carbides were frequently found in MC(ID). The influence of C, Al, Ti, and B on the above phase reactions and solidified structure was also clarified.

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中島一磨, 小林睦弘, 磯部浩一, 渡辺健彦, 矢萩正人, 宮地博文, 望月俊男, 長谷川晃

pp. 139-141

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製鋼・基礎

鉄と鋼 Vol.47(1961), No.10

製鋼基礎

鉄と鋼 Vol.51(1965), No.10

Decarburization and Denitrogenization of Iron and Iron-Chromium Alloys by Plasma Jet of Hydrogen-Argon Gas Mixture

鉄と鋼 Vol.62(1976), No.1

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21 Nov. (Last 30 Days)

In-situ Observation of Precipitation and Growth of MnS Inclusions during Solidification of a High Sulfur Steel

ISIJ International 早期公開
Measurement of Bubble Size Distribution and Generation Position of Bubbles Generated during Smelting Reduction of Iron Oxide-containing Slag

ISIJ International 早期公開
Injection of hydrogenous gases into the blast furnace tuyeres for reducing CO₂ emissions: a review

ISIJ International 早期公開
Development of a Low-carbon Sintering Process Technology and Its Application to a Pilot-scale Sintering Testing

ISIJ International Vol.64(2024), No.13
凝固過程における溶鋼中からAl₂O₃上へのMnSの晶出挙動

鉄と鋼早期公開
Molecular dynamics simulation of viscosity of the CaO, MgO and Al₂O₃ melts

ISIJ International 早期公開
Fe–(0.5–2.0)%Al–2.0%Mn合金の一方向凝固におけるAlNの晶出挙動に及ぼすAl濃度の影響

鉄と鋼早期公開
凝固過程のミクロ偏析による溶質濃度分布の定量的理解

鉄と鋼早期公開
SOKD: A soft optimization knowledge distillation scheme for surface defects identification of hot-rolled strip

ISIJ International 早期公開
Reduction and Carburization Behaviors of Iron Oxide Composite with Iron Carbide and Free Carbon

ISIJ International 早期公開

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鉄と鋼 Vol. 71 (1985), No. 1

キーワードランキング

reduction caco3 in electric furnace

kinetics of decarburization of liquid iron with high concentration ofcarbon

kinetics of decarburization of liquid iron by ar-coz gasmixture

ahss

charpy impact chemistry

dual phase steel

foamy slag in eaf

kinetics of decarburization of liquid iron by

ladle furnace flicker

scm440

鉄と鋼 Vol. 71 (1985), No. 1

Recent Trend of Squeeze Casting

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New Technology of Iron Ore Mining

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Shearing Techniques and Their Resulting Sheared Surfaces

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Influence of Hot Metal Flow on the Heat Transfer in a Blast Furnace Hearth

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Burden Distribution in Shaft Furnace for Direct Reduction of Iron Ores

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A Simulation Model for Gas Flow in Direct Reduction Furnace for Iron Ores

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Solubility and Dissolution Rate of Water Vapor in Liquid CaO-SiO2-Al2O3 Slags

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Rate of Dephosphorization of Liquid Iron by the Flux of Na2O-SiO2 System

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Rate of Absorption of Injected Nitrogen in Molten Iron

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Prediction of the Formation Region of Eutectic NbC in a Large 12Cr-Mo-V-Nb Steel Ingot

SNSによる共有

The Effect of Tensile Strength and Ductility on High Temperature Low Cycle Fatigue of Cast Ni-base Superalloys

SNSによる共有

The Role of Simulated HTGR Helium on the Low Cycle Fatigue Behavior of Ni-Cr-W Alloys

SNSによる共有

Properties of Induction Heat-treated High Strength Spring Wire

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Effects of Alloying Elements on Embrittlement of 15Cr-26Ni-1.25Mo Type Precipitation Hardening Alloy

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Creep Fracture Mechanism Maps Based on Creep Rupture Tests up to about 100 000 h for Type 316 Stainless Steel

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Service Life Prediction of Industrial Pipe-line

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Solidification Behavior of a Nickel-base Superalloy, IN-100

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抄録

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論文アクセスランキング

In-situ Observation of Precipitation and Growth of MnS Inclusions during Solidification of a High Sulfur Steel

Measurement of Bubble Size Distribution and Generation Position of Bubbles Generated during Smelting Reduction of Iron Oxide-containing Slag

Injection of hydrogenous gases into the blast furnace tuyeres for reducing CO2 emissions: a review

Development of a Low-carbon Sintering Process Technology and Its Application to a Pilot-scale Sintering Testing

凝固過程における溶鋼中からAl2O3上へのMnSの晶出挙動

Molecular dynamics simulation of viscosity of the CaO, MgO and Al2O3 melts

Fe–(0.5–2.0)%Al–2.0%Mn合金の一方向凝固におけるAlNの晶出挙動に及ぼすAl濃度の影響

凝固過程のミクロ偏析による溶質濃度分布の定量的理解

SOKD: A soft optimization knowledge distillation scheme for surface defects identification of hot-rolled strip

Reduction and Carburization Behaviors of Iron Oxide Composite with Iron Carbide and Free Carbon

詳細検索

Solubility and Dissolution Rate of Water Vapor in Liquid CaO-SiO₂-Al₂O₃ Slags

Rate of Dephosphorization of Liquid Iron by the Flux of Na₂O-SiO₂ System

Injection of hydrogenous gases into the blast furnace tuyeres for reducing CO₂ emissions: a review

凝固過程における溶鋼中からAl₂O₃上へのMnSの晶出挙動

Molecular dynamics simulation of viscosity of the CaO, MgO and Al₂O₃ melts