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鉄と鋼
Vol. 52 (1966), No. 6

鉄と鋼 Vol. 52 (1966), No. 6

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オンライン版ISSN:	1883-2954
冊子版ISSN:	0021-1575
発行機関:	The Iron and Steel Institute of Japan

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キーワードランキング

21 Dec. (Last 30 Days)

鉄と鋼 Vol. 52 (1966), No. 6

随想

雀部高雄

pp. 921-922

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Theoretical Consideration on Coke Ratio of the Blast Furnace Operation

Fumitada NAKATANI, Tetsuya MUKAI, Fumio NAKAMURA

pp. 923-946

抄録

It is an obvious misinterpretation that GRÜNER'S theory-the unconditionally dominant position of indirect reduction-has been believed to be correct.
In this report, the authors criticized the previous theories and established a new one on Coke (or Carbon) Ratio in the blast furnace operation.
Three following conditions should at least be satisfied in order that the blast furnace operation can be performed, that is to say, the conditions of mass balance, gas-solid equilibrium and thermal balance.
We can express the reducing reaction of iron are in the blast furnace by the equation, FeOn+X₁C+X₂CO=Fe+CO+xCO+yCO₂ (1)
Giving top gas ratio (γ=x/y=CO/CO₂), X₂=an and the rate in fraction of direct reduction (D. R), then the required carbon (X₁+X₂) is shown as follows:
X₁×X₂=n (1+γ)(1-D.R) kg atom C/kg atom Fe (2)
where, n is the rate of kg atom Oxygen per kg atom Iron in the burden.
Supposing iron are only consists of pure hematite, accordingly n=1.50, then the required carbon can be calculated by substituting the values of γ and D.R. into the equation (2).
Carbon ratio expressed by the equation (2) from point of view of carbon balance must be limited in consideration of gas-solid equilibrium and thermal balance. We investigated in detail these conditions, considered “Carbon Ratio Curved Surface” in the blast furnace operation and then decided its limitation.
And we showed clearly that the attainable limitation when the furnace operation was performed ideally was about D.R 39% and γ 0.95, then carbon ratio gained was about 410kg per ton pig at blast temperature 1000°C.
Therefore, the furnace operation should be performed at as near the value mentioned above as possible.
After all, the equation (2) shows decreasing coke ratio of blast furnace operation with increasing D.R at constant γ and decreasing γ at constant D.R.
We showed also the Equal Carbon Ratio Curve quantitatively.
It can be concluded that we should abandon the idea of giving the unconditionally dominant position to indirect reduction and pay attention to direct reduction which plays an important part in the blast furnace.

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鉄と鋼 Vol.53(1967), No.9

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Interaction between Solute Elements at Any Given Concentration in Homogeneous Multicomponent Solution

Toshisada MORI, Akira MORO-OKA

pp. 947-958

抄録

The general relationship between activities and activity coefficients based on Raoultian and Henrian reference states at any given concentration was derived and the relationship among concentration quotients of solute activity at constant concentration and at constant concentration ratio was also derived.
WAGNER type theoretical series expansion is valid at any concentrated solution, and Taylor series expansion using the interaction parameters at constant concentration ratio is also possible. The conversion equations between several kinds of interaction parameters valid at any given concentration in a multicomponent solution were derived by the aid of Gibbs-Duhem equation and Maxwell cross differentials.
In a ternary system 1-2-3, the following relations were obtained at any given concentration:
where γ(or f) is the activity coefficient in mole fraction basis (or in weight percent basis), N (or X) is the mole fraction (or weight percent), M is the atomic weight and the underscript signifies the component to be kept constant. It was also shown that the interaction parameter at constant mole fraction ratio β(j) i=β(i) j is valid at the condition N_i=N_j, and from this it follows that δlnγ1/δN₂=δnγ₂/δN₁at N₁=N₂=0.5 in a binary solution. A discussion was made concerning the solution ironnickel as an example.

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The Deoxidation with Titanium in Liquid Iron

Hirotaka CHINO, Yasushi NAKAMURA, Eiichi TSUNETOMI, Kiyoshi SEGAWA

pp. 959-966

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The interrelations among titanium, oxygen in liquid iron and deoxidation products at 1550°, 1600° and 1650*deg;C were studied.
In this experiment, two effective techniques were developed. One is the use of a thermocouple protected from high frequency interference by an Mo tube inserted for the automatic temperature control and measurement. The other is the application of the Peeling method for the sampling of the deoxidation products for identification.
The following results were obtained.
(1) Primary deoxidation products:
Corresponding the contents of titanium in liquid iron, a few kinds of the primary deoxidation products were identified as follows.
Ti₃O₅ (anosovite): 0.001<[%Ti]<0.2
Ti₂O₃ (α-Al₂O₃ type): 0.2<[%Ti]<2
At higher titanium contents TiO seems to be produced.
(2) Deoxidation equilibrium constant:
In the range of 0.001 to 0.1% Ti and at 1550 to 1650, the reaction was as follows.Ti₃O₅ (s) =3Ti+5O log K′=-41, 470/T+3.40

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Effect of Addition of Ti and B on Mn-Si, Mn-Si-Cr and Mn-Si-Mo Steels

鉄と鋼 Vol.49(1963), No.2

On the Behavior of Several Kinds of Oxide Inclusion in Steels during Hot-rolling

鉄と鋼 Vol.54(1968), No.9

Effect of Alloying Elements on Interfacial Tension between Molten Steel and Slag

鉄と鋼 Vol.53(1967), No.7

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Recent Development on the Isolation of Inclusions (Precipitates) in Steel

Kiyoshi SEGAWA

pp. 967-980

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Effect of Addition of Ti and B on Mn-Si, Mn-Si-Cr and Mn-Si-Mo Steels

鉄と鋼 Vol.49(1963), No.2

On the Behavior of Several Kinds of Oxide Inclusion in Steels during Hot-rolling

鉄と鋼 Vol.54(1968), No.9

Effect of Alloying Elements on Interfacial Tension between Molten Steel and Slag

鉄と鋼 Vol.53(1967), No.7

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Development in Recent Steel-Making Technology in Japan

Toshiro INOUE

pp. 981-988

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Development of Installation and Technique in Wire Rod Mill

Kokichi ASADA

pp. 989-1000

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Research and Development of a High Quality Wire Rod for Cold Heading and Its Mass Production

鉄と鋼 Vol.61(1975), No.11

Rapid Spheroidization Annealing Technique of Structural Steel Wire Rod

鉄と鋼 Vol.69(1983), No.10

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Properties of Pure Iron Deformed by Impact Tension

Seita SAKUI, Yoshiro KOYASU

pp. 1001-1001

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pp. 1002-1005

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資料室だより

pp. 1006-1006

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鉄鋼ニューズ

pp. 1008-1009

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21 Dec. (Last 30 Days)

Wettability of CaS against molten iron at 1873 K

ISIJ International 早期公開
凝固過程における溶鋼中からAl₂O₃上へのMnSの晶出挙動

鉄と鋼早期公開
Reduction and Melting Behaviors of Iron Oxide Composite with Carbon Deposited Using CO-CO₂-H₂ Mixed Gas

ISIJ International 早期公開
In-situ Observation of Precipitation and Growth of MnS Inclusions during Solidification of a High Sulfur Steel

ISIJ International Vol.64(2024), No.14
Perspectives on the Promising Pathways to Zero Carbon Emissions in the Steel Industry toward 2050

ISIJ International 早期公開
モデル材料を用いた凝固過程における介在物生成挙動のその場観察

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Transition behavior of gas containing suspension from solid-like to liquid-like flows

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A hot rolling full process rolling force prediction method based on transfer learning and Inception-LSTM neural network

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Slag-steel reactions in the refining of Advanced High-Strength Steel

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Chemical and Mechanical Factors on Phosphorus Dissolution Behavior from P-concentrated Slag

ISIJ International Vol.64(2024), No.14

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鉄と鋼 Vol. 52 (1966), No. 6

キーワードランキング

hydrogen reduction of iron ore

gasification

characterization of coal and biomass based on kinetic parameter distributions for pyrolysis

kinetics of decarburization of liquid iron with high concentration ofcarbon

mechanisms of liquefaction and pyrolysis reaction of biomass

hydrogen reduction

steel

19al6mg

automotive wheel

deguchi

鉄と鋼 Vol. 52 (1966), No. 6

随想

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Theoretical Consideration on Coke Ratio of the Blast Furnace Operation

SNSによる共有

Interaction between Solute Elements at Any Given Concentration in Homogeneous Multicomponent Solution

SNSによる共有

The Deoxidation with Titanium in Liquid Iron

SNSによる共有

Recent Development on the Isolation of Inclusions (Precipitates) in Steel

SNSによる共有

Development in Recent Steel-Making Technology in Japan

SNSによる共有

Development of Installation and Technique in Wire Rod Mill

SNSによる共有

Properties of Pure Iron Deformed by Impact Tension

SNSによる共有

抄録

SNSによる共有

資料室だより

SNSによる共有

鉄鋼ニューズ

SNSによる共有

論文アクセスランキング

Wettability of CaS against molten iron at 1873 K

凝固過程における溶鋼中からAl2O3上へのMnSの晶出挙動

Reduction and Melting Behaviors of Iron Oxide Composite with Carbon Deposited Using CO-CO2-H2 Mixed Gas

In-situ Observation of Precipitation and Growth of MnS Inclusions during Solidification of a High Sulfur Steel

Perspectives on the Promising Pathways to Zero Carbon Emissions in the Steel Industry toward 2050

モデル材料を用いた凝固過程における介在物生成挙動のその場観察

Transition behavior of gas containing suspension from solid-like to liquid-like flows

A hot rolling full process rolling force prediction method based on transfer learning and Inception-LSTM neural network

Slag-steel reactions in the refining of Advanced High-Strength Steel

Chemical and Mechanical Factors on Phosphorus Dissolution Behavior from P-concentrated Slag

詳細検索

凝固過程における溶鋼中からAl₂O₃上へのMnSの晶出挙動

Reduction and Melting Behaviors of Iron Oxide Composite with Carbon Deposited Using CO-CO₂-H₂ Mixed Gas