蒸気輸送法による4CaO·P2O5および3CaO·P2O5の標準生成ギブズエネルギーの直接測定
山末 英嗣, 清水 謙治, 永田 和宏
pp. 169-176
抄録
The standard Gibbs energy changes of the following reactions have been measured by using transpiration method;
4CaO∙P2O5(s) + 5C(s) = 4CaO(s) + P2(g) + 5CO(g)
ΔGo/kJ = 1624 – 0.953T (± 2.7), (1373 < T/K < 1573)
4(3CaO∙P2O5)(s) + 5C(s) = 3(4CaO∙P2O5)(s) + P2(g) + 5CO(g)
ΔGo/kJ = 1946 – 1.193T (± 0.9), (1448 < T/K < 1523)
The standard Gibbs energies of the formation of 4CaO∙P2O5 (ΔGof,(4CaO∙P2O5)) and 3CaO∙P2O5 (ΔGof,(3CaO∙P2O5)) have been derived as follows;
ΔGof(4CaO∙P2O5)/kJ mol–1 = – 4765 + 0.965 T, (1373 < T/K < 1573)
ΔGof(3CaO∙P2O5)/kJ mol–1 = – 4200 + 0.912 T, (1448 < T/K < 1523)
The reasons for discrepancies from reported values were discussed from the view point of whether the activity of phosphorus is measured directly or not.
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