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鉄と鋼
Vol. 54 (1968), No. 7

鉄と鋼 Vol. 54 (1968), No. 7

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オンライン版ISSN:	1883-2954
冊子版ISSN:	0021-1575
発行機関:	The Iron and Steel Institute of Japan

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キーワードランキング

21 Dec. (Last 30 Days)

鉄と鋼 Vol. 54 (1968), No. 7

随想

三宅川隆三

pp. 761-762

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Thermodynamic Properties of Niobium Carbides and Nitrides in Steels

Toshisada MORI, Masaharu TOKIZANE, Ko YAMAGUCHI, Eihachiro SUNAMI, Yoshiyuki NAKAZIMA

pp. 763-776

抄録

The crystallographic structure and the chemical composition of precipitated δ-phase, δ′-phase and ε-phase were extensively investigated on those specimens which had been prepared from vacuum melted high-purity Fe-Nb-C, Fe-Nb-N and Fe-Nb-C-N alloys containing niobium up to 0.95%. The specimens were solution treated at 1300 or 1350°C for 2hr, and then these were again quenched into water after long time holding at respective temperatures of 1000 to 1300°C. The quantitative determination of soluble-niobium, -carbon and -nitrogen was also investigated in order to calculate the solubility products of niobium-carbide and -nitride in austenite. Results obtained are as follows;
1) The chemical composition of pure δ-niobium-carbide precipitates was determined to be NbC_0.87 though the precipitated δ-phase was not pure carbide but carbonitride even in the Fe-Nb-C alloys containing little nitrogen.
2) The precipitated δ′-nitride in Fe-Nb-N alloys containing little carbon was substantially carbonitride containing a little amount of carbon, while the precipitated ε-nitride was estimated to be a pure niobium-nitride NbN.
3) The solubility products of niobium-carbide and -nitride in austenite were given respectively by the following equations;
log [%Nb][%C]^0.87=-7, 700/T+3.18
log [%Nb][%N]=-10.150/T+3.79
4) It has been proved that oxygen has the stronger affinity to niobium than carbon and nitrogen in austenite. The preferential precipitation of a little amount of tapiolite [(Fe, Nb) O₂ or FeO. Nb₂O₅] was recognized in all specimens.

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On the Isothermal Age-hardening of Fe-Ni-Mn Martensitic Alloys

Minoru TANAKA, Tommo SUZUKI, Masayoshi YODOGAWA

pp. 776-786

抄録

The age-hardening behaviours of the Fe-Ni-Mn martensitic alloys have been studied in relation to hardness, microstructure, lattice constant, electrical resistivity and magnetic properties comparing with those of the non-age-hardenable Fe-Ni and Fe-Mn martensitic alloys. The results obtained in this study are summarized as follows.
(1) In the age-hardenable Fe-Ni-Mn alloys, the matrix becomes etchable accompanying the reveal of fine particles during age-hardening. In this hardening stage, the electrical resistivity decreases and the lattice constant of matrix is maintained in almost constant while the half width of X-ray diffraction line increases. The reversion can be observed in the age-hardened Fe-Ni-Mn alloys.
(2) In the non-age-hardenable Fe-Ni alloy, austenite appears during aging and grows in lameller and the half width decreases abruptly on a short time aging.
(3) Although the age-hardening of Fe-Ni-Mn martensitic alloys cannot be ascribed to one factor, it seems likely that the strain hardening due to the formation of the coherent precipitate or zone in the matrix is a major factor. It is difficult to consider that such coherent precipitate or zone will be formed in the non age-hardenable Fe-Ni or Fe-Mn martensitic alloys.
(4) The formation of such precipitate or zone will be possible when the miscibility gap island can be assumed in the martensitic matrix of Fe-Ni-Mn alloys.

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Automatic Control and Automatic Change of Hot Stove

鉄と鋼 Vol.50(1964), No.5

Effect of Ausforming on the Carbide Precipitation of Fe-Mo-C Alloy

鉄と鋼 Vol.53(1967), No.11

Relationship between Deep Drawability and Textures in Low Carbon Steel Sheets

鉄と鋼 Vol.54(1968), No.11

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Determination of Zinc in Steelmaking Dust

Shigeo WAKAMATSU

pp. 787-795

抄録

A simple chelatometric titration method for the determination of zinc in steel making dust has been developed.
Zinc form negatively charged chloride complex which is adsorbed by the strongly basic anion exchange resin. Maximum adsorption of zinc is obtained in 2N HCl. In this medium most elements with which zinc are associated in dust are not adsorbed by the resin. It is therefore possible to separate zinc from iron, aluminium, manganese, calcium, magnesium, chromium and nickel.
Zinic is then eluted from the resin with 0.3N HNO₃, and titrated with EDTA using EBT as the indicator. Part of iron, copper, tin, lead and arsenic are adsorbed on the resin, but a subsequent EDTA titration procedure is described which obviates their interference.
The proposed has the advantage of speed, yet has the same accuracy as the gravimetric method.

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Construction and Operation of Fukuyama Iron Works, Nippon Kokan K. K

Hiroshi NAKANO

pp. 796-816

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Construction of a giant iron works was planned by Nippon Kokan with a crude steel production of ten million tons as the final target, to cope with increasing competition in domestic and foreign marketsfor the future development of the steel industry of Japan. Another reason of this decision was the fact that the crude steel production at the three iron works in Tokyo-Yokohama area was limited to five million tons because of the local restrictions.
Company policy for this construction was directed toward the adoption of largest and most highly automated facilities and a layout permitting the most rational transportation. An area of 7.26million m² was selected from among many possible sites of construction within Japan at the coast of Fukuyama in compliance with this policy. Reclamation was launched in January 1962. The first period construction was completed in summer 1966 with the production of sheets as objective. The crude steel production has reached in June 1967 a level of two million tons. The second period construction isalready underway, and a production system comprising hot and cold rolled sheets and wide plates corresponding to a crude steel production of four million tons will be established at the beginning of 1968.

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An Investigation of the Sintering Machine to be Enlarged and Modernized

Kumao UESHIMA

pp. 817-836

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Application of Special Instrumental Analysis to the Analysis of Iron and Steel

Hidehiro GOTO, Kichinosuke HIROKAWA

pp. 837-844

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Reconstruction of the Three-dimensional Ferrite–austenite Microstructure and Crystallographic Analysis in the Early Stage of Reverse Phase Transformation in an Fe–Mn–C Alloy

ISIJ International Vol.58(2018), No.2

Thermodynamic Properties of Niobium Carbides and Nitrides in Steels

鉄と鋼 Vol.54(1968), No.7

Effect of CaO/Al₂O₃ Ratio of Ladle Slag on Formation Behavior of Inclusions in Mn and V Alloyed Steel

ISIJ International Vol.58(2018), No.1

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pp. 845-849

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21 Dec. (Last 30 Days)

Wettability of CaS against molten iron at 1873 K

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鉄と鋼早期公開
Reduction and Melting Behaviors of Iron Oxide Composite with Carbon Deposited Using CO-CO₂-H₂ Mixed Gas

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In-situ Observation of Precipitation and Growth of MnS Inclusions during Solidification of a High Sulfur Steel

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Perspectives on the Promising Pathways to Zero Carbon Emissions in the Steel Industry toward 2050

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Transition behavior of gas containing suspension from solid-like to liquid-like flows

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A hot rolling full process rolling force prediction method based on transfer learning and Inception-LSTM neural network

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Slag-steel reactions in the refining of Advanced High-Strength Steel

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鉄と鋼 Vol. 54 (1968), No. 7

キーワードランキング

hydrogen reduction of iron ore

gasification

characterization of coal and biomass based on kinetic parameter distributions for pyrolysis

kinetics of decarburization of liquid iron with high concentration ofcarbon

mechanisms of liquefaction and pyrolysis reaction of biomass

hydrogen reduction

steel

19al6mg

automotive wheel

deguchi

鉄と鋼 Vol. 54 (1968), No. 7

随想

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Thermodynamic Properties of Niobium Carbides and Nitrides in Steels

SNSによる共有

On the Isothermal Age-hardening of Fe-Ni-Mn Martensitic Alloys

SNSによる共有

Determination of Zinc in Steelmaking Dust

SNSによる共有

Construction and Operation of Fukuyama Iron Works, Nippon Kokan K. K

SNSによる共有

An Investigation of the Sintering Machine to be Enlarged and Modernized

SNSによる共有

Application of Special Instrumental Analysis to the Analysis of Iron and Steel

SNSによる共有

抄録

SNSによる共有

論文アクセスランキング

Wettability of CaS against molten iron at 1873 K

凝固過程における溶鋼中からAl2O3上へのMnSの晶出挙動

Reduction and Melting Behaviors of Iron Oxide Composite with Carbon Deposited Using CO-CO2-H2 Mixed Gas

In-situ Observation of Precipitation and Growth of MnS Inclusions during Solidification of a High Sulfur Steel

Perspectives on the Promising Pathways to Zero Carbon Emissions in the Steel Industry toward 2050

モデル材料を用いた凝固過程における介在物生成挙動のその場観察

Transition behavior of gas containing suspension from solid-like to liquid-like flows

A hot rolling full process rolling force prediction method based on transfer learning and Inception-LSTM neural network

Slag-steel reactions in the refining of Advanced High-Strength Steel

Chemical and Mechanical Factors on Phosphorus Dissolution Behavior from P-concentrated Slag

詳細検索

凝固過程における溶鋼中からAl₂O₃上へのMnSの晶出挙動

Reduction and Melting Behaviors of Iron Oxide Composite with Carbon Deposited Using CO-CO₂-H₂ Mixed Gas