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鉄と鋼 Vol. 70 (1984), No. 1

ISIJ International
belloff

Grid List Abstracts
オンライン版ISSN: 1883-2954
冊子版ISSN: 0021-1575
発行機関: The Iron and Steel Institute of Japan

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  1. Vol. 110 (2024)

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  5. Vol. 106 (2020)

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  6. Vol. 105 (2019)

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  8. Vol. 103 (2017)

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  9. Vol. 102 (2016)

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  10. Vol. 101 (2015)

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  11. Vol. 100 (2014)

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  12. Vol. 99 (2013)

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  13. Vol. 98 (2012)

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  14. Vol. 97 (2011)

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  15. Vol. 96 (2010)

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  16. Vol. 95 (2009)

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  17. Vol. 94 (2008)

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  18. Vol. 93 (2007)

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  19. Vol. 92 (2006)

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  20. Vol. 91 (2005)

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  21. Vol. 90 (2004)

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  22. Vol. 89 (2003)

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  23. Vol. 88 (2002)

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  24. Vol. 87 (2001)

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  25. Vol. 86 (2000)

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  26. Vol. 85 (1999)

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  27. Vol. 84 (1998)

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  28. Vol. 83 (1997)

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  29. Vol. 82 (1996)

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  30. Vol. 81 (1995)

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  31. Vol. 80 (1994)

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  32. Vol. 79 (1993)

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  33. Vol. 78 (1992)

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  34. Vol. 77 (1991)

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  35. Vol. 76 (1990)

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  36. Vol. 75 (1989)

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  37. Vol. 74 (1988)

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  38. Vol. 73 (1987)

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  39. Vol. 72 (1986)

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  40. Vol. 71 (1985)

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  41. Vol. 70 (1984)

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  42. Vol. 69 (1983)

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  43. Vol. 68 (1982)

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  44. Vol. 67 (1981)

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  45. Vol. 66 (1980)

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  46. Vol. 65 (1979)

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  47. Vol. 64 (1978)

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  48. Vol. 63 (1977)

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  49. Vol. 62 (1976)

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  50. Vol. 61 (1975)

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  51. Vol. 60 (1974)

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  52. Vol. 59 (1973)

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  53. Vol. 58 (1972)

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  54. Vol. 57 (1971)

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  55. Vol. 56 (1970)

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  56. Vol. 55 (1969)

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  57. Vol. 54 (1968)

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  58. Vol. 53 (1967)

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  59. Vol. 52 (1966)

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  60. Vol. 51 (1965)

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  61. Vol. 50 (1964)

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  62. Vol. 49 (1963)

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  63. Vol. 48 (1962)

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  64. Vol. 47 (1961)

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  65. Vol. 46 (1960)

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  66. Vol. 45 (1959)

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  67. Vol. 44 (1958)

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  68. Vol. 43 (1957)

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  69. Vol. 42 (1956)

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  70. Vol. 41 (1955)

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    11. No.2
    12. No.1

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21 Nov. (Last 30 Days)

鉄と鋼 Vol. 70 (1984), No. 1

A High Dimensional and Automated Rolling Technology for Rod and Bar Gauge Performance

Motoh ASAKAWA, Hisayoshi HAMAMATSU

pp. 16-22

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Recent Development in Steels for Ice Breaking Ships and Ice Strengthened Off Shore Structures

Junichi TANAKA, Mamoru SATO

pp. 23-36

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Deterioration of Blast Furnace Coke by CO2 Gasification

Tetsu NISHI, Hiroshi HARAGUCHI, Yoshiaki MIURA

pp. 43-50

抄録

The deterioration of coke in the blast furnace was taken as the change in coke size with the reaction between the coke and CO2 gas. To clarify this reaction mechanism, a series of experiments were carried out, using apparatus for measuring coke strength after CO2 reaction. The findings obtained are as follows:
(1) The process of progress of the reaction between the coke and CO2 gas can be analyzed by a single-particle model.
(2) As a result, a homogeneous-phase model or an unreacted-core model may be considered to represent the reaction type of lump coke.
(3) When coke contains a large amount of isotropic textures, the reaction proceeds at the surface. The type of this reaction is close to that represented by the unreacted-core model.
(4) When coke has a high porosity, the CO2 gas permeates the inside of coke lump along the pores. The type of this reaction is close to that represented by the homogeneous-model.
(5) The difference between these two types of reaction depends on the matrix nature and structure of coke.
(6) Based on the above findings, the conditions required of coke that is not readily reduced in size by CO2 gasification are proposed.

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Development and Application of Blast Furnace Operation Control System in Hirohata Works

Takahiro FUKUDA, Fumio NAITO, Masataka HIMEDA, Tetsuro SUETAKI, Michitaka NISHIO, Kiyoshi NISHIKAWA, Mitsuo KANBE

pp. 51-57

抄録

For the efficient blast furnace operation, a computer system having following functions was developed and has been used in Hirohata works.
(1) Control function of gas flow distribution : The accuracy of gas flow detection can be improved by this function, and the efficient gas utilization has been achieved.
(2) Control function of heat balance : This function consists of estimation model and operational guide for heat balance operation, and it helps stabilization of hot metal quality.
(3) Prevention function of abnormal condition : The abnormal condition can be forecasted and prevented by this function, and the stable condition in blast furnace has been obtained.
(4) Function of operation analysis : This function supports other functions by rapidly analysing operational data.
These functions have been refined according to the change of circumstances successively, and contributing to efficient blast furnace operation.

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Gas-phase Mass Transfer by Impinging Jet on Liquid Surface in Crucible

Hiroshi SAITO, Akinori YOSHIZAWA, Tanekazu SOMA

pp. 58-64

抄録

Average mass transfer between an impinging laminar jet of gas and a liquid surface in a crucible was studied.
The experiments were carried out in the following systems;
a) H2O (1)-CO2 (g), C2H5OH (l)-H2 (g) and H2O (l)-CO2 (g) systems with known diffusion coefficients DAB (m2/s) near room temperature (1060°C),
b) FeCl2-(l)-N2 (g) system with unknown diffusion coefficient in high temperature (700930°C).
(1) For the average Sherwood number Sh (≡kdc/ DAB), the correlation was obtained as
Sh=m (rc/d)-1Re0.87 Sc0.66, (m= 0.56 ± 0.06)
by the experiment on systems a) under condition;
4≤Re≤800, 0.5≤Sc≤1.24, 3.17≤(rc/d)≤9.5.
(2) For the system b), Sh could also be expressed by the above equation above for 20≤Re≤200, rc/d= 2.42.
(3) Temperature dependence of the diffusion coefficient of FeCl2 (g) in N2 (g) for 700 to 930°C, 1 atm was obtained as
DFeCl2- N2=a (T/273)2.0×10-4, (a= 0.31±0.01) (m2/s)
based on the similarity between experiments a) and b) for gas-phase mass transfer.

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Effects of Ti, V, Cr, Mn, Co, Ni, Cu, Nb, Mo, and W on the Activity of Phosphorus in Liquid Iron

Shiro BAN-YA, Nobutoshi MARUYAMA, Yukio KAWASE

pp. 65-72

抄録

The vapor pressure of phosphorus on liquid Fe-P-j (j=Ti, V, Cr, Mn, Co, Ni, Cu, Nb, Mo, or W) alloys has been measured by the transportation method at 1 673K.
The results obtained are treated by the model of interstitial solution proposed by J. CHIPMAN, and the effects of alloying elements on the activity coefficient of phosphorus in liquid iron are determined by assuming that all the alloying elements studied in the present work are substitutional.
The interaction parameters obtained in this work are summarized as follows:
εTlP=-11.0±2.1, εVP=-8.67±2.79
εCrP=-9.34±2.26, εMnP=-7.17±1.16
εCoP=-1.17±1.04, εNiP=-1.47±0.88
εCuP=-9.42±2.86, εNbP=-16.1±1.6
εMoP=-7.26±1.78, εWP=-19.4±3.9

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Rate of Reduction of MnO in Slag by Liquid Iron Containing Carbon

Nobuya SHINOZAKI, Kaichiro ISHIDO, Katsumi MORI, Yasuji KAWAI

pp. 73-80

抄録

Rate of reduction of MnO in slag by liquid iron was studied at mainly 1 600°C. Experiments were carried out with liquid iron containing carbon from 0.8% to saturation and CaO-SiO2-Al2O3 slag containing about 5%MnO. Evolution of CO gas was observed with X-ray technique. Reduction of MnO in slag took place by exchange reaction with iron and reaction with carbon in iron.
Reaction rate was interpreted by the rate equation derived from the assumption that the reaction was controlled by transfers of reacting components.
Calculated mass transfer coefficient of MnO in slag was in the same order of the value obtained for the study of rate of transfer of manganese between liquid iron free of carbon and slag. Therefore, it was considered that the stirring of slag phase by CO bubbles was not so intensive.

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Accumulation and Countermeasures for Diminishing of Non-metallic Inclusions in the Sub-surface of Continuously Cast Slabs

Tadanobu KOMAI, Ikuro NODA, Katsuhiko NORO, Kazuyuki IGA, Jun OSHIDA, Toshio HORI

pp. 81-88

抄録

Studies on accumulation of non-metallic inclusion in sub-surface of continuously cast slabs were carried out. Results obtained are as follows:
(1) Accumulation of alumina cluster in sub-surface of slabs occurs at the stagnant zone of the upward streams from the immersion nozzle in mold. The degree of the above-mentioned accumulation of alumina can be decreased by improving absorption capasity of mold flux.
(2) Accumulation of alumina cluster in the sub-surface of slabs is caused by entrapping in solidifing shell near the meniscus of alumina, which is carried up to the surface of molten steel in the mold and can not be absorbed enough in the mold flux.
(3) Argon gas bowing nozzle is effective in reduction of alumina cluster in sub-surface of slabs.
(4) Degree of surface defects, caused by fluctuation of surface level of molten steel, can be explained by the products of its fluctuation velocity and its fluctuation width.

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Mechanical Properties of Steel Plates Produced by the On-line Accelerated Cooling

Koshiro TSUKADA, Kazuaki MATSUMOTO, Yoshitaka YAMAZAKI, Kenji HIRABE, Kazuyoshi ARIKATA, Kenji TAKESHIGE

pp. 89-95

抄録

The plate mill on-line accelerated cooling (OLAC) process is a controlled cooling process characterized by interrupted accelerated cooling in the transformation temperature range after hot-rolling, and subsequent air cooling to room temperature. To optimize production conditions, the effects of rolling conditions, cooling conditions and chemical composition on the mechanical properties of the controlled cooled plates were studied in comparison with controlled rolled (CR) plates. The controlled cooling process could increase strength withont sacrificing toughness, resulting in improved weldability because of decrease in carbon and alloying elements. The beneficial effect was attributed to the fine ferrite and finely dispersed bainite microstructure. The toughness and strength of the controlled cooled plates were determined by the CR conditions before cooling, and the subsequent cooling conditions, respectively. The optimum cooling conditions were as follows : the initial cooling temperature above Ar3, the final cooling temperature ranging from 500 to 600°C, and the cooling rate from 3 to 15°C/s. The controlled cooled plates produced under the optimum conditions had good mechanical properties, equal or superior to those of the CR plates finish-rolled in the (γ+ α) regions, even with the remarkably reduced separation. The production results are also described herein.

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Influence of Rolling Temperature on the Recrystallization Texture in Fe-N Alloy

Kohsaku USHIODA, Mitsunobu ABE

pp. 96-103

抄録

In the process of rolling and subsequent annealing, the influence of rolling temperature on the recrystallization texture has been investigated using Fe-0.01 wt% N alloy having the initial grain size of 80μm. Coarsely arranged and wide deformation bands with {110} <001> and {100} <011> orientations are formed after 300°-400°C rolling which is under the condition of dynamic strain aging. Because recrystallized grains with these orientations are preferentially nucleated during annealing at the deformation band, {110} <001> recrystallization textures with a minor intensity of {100} are obtained after annealing. On the other hand, deformation twins formed by-196°C rolling are considered to act as the preferential nucleation site of {211} recrystallized grains and consequently provide {211} <011> recrystallization textures. At other rolling conditions where the formation of deformation bands and deformation twins is not observed, {111} recrystallization textures are developed by the preferential nucleation of recrystallized grains with {111} near existing grain boundaries.

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Temperature Dependence of Hydrogen Diffusivity of 2 1/4, Cr-1Mo Steel

Tadaomi FUJII, Kazuo NOMURA

pp. 104-111

抄録

Temperature dependence of hydrogen diffusivity in as-quenched 2 1/4Cr-1 Mo steel at temperatures of 25 to 300°C was investigated by a glycerine displacement increasing (GDI) method and a electrochemical method. In the determination of residual hydrogen by GDI method, hydrogen was charged at a austenitic temperature range under a hydrogen atmosphere and was discharged in isothermal baths at temperatures of 45 to 300°C.
1) The hydrogen evolution curves measured by GDI method at 45°C and by a electrochemical method at 25°C in cylindrical specimens agree well with a analytical solution given from Fick's Law.
2) Measured hydrogen diffusivities in as-quenched 2 1/4Cr-1 Mo steel agree considerably well with the values calculated from a theoretical equation based on a hydrogen trap theory. The apparent hydrogen diffusivity, D, is given as the following equation:
D=Dl / (1+κ) (cm2/s)
where, Dl= 7.6×10-4 exp (-2 300/R T) (cm2/s)
κ= 1.05 × 10-4 exp (7 100/RT)
R: gas constant
T: absolute temperature

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Immunization of Type 304 Stainless Steels to Intergranular Corrosion by Thermomechanical Treatment

Kiyoshi KIUCHI, Tatsuo KONDO

pp. 112-119

抄録

Simple and practical countermeasures to intergranular corrosion of normal commercial heats of SUS 304 stainless steels were developed by utilizing the microstructural features of the material aged after plastic deformation without modifying alloy composition. In this method, manufacturing process was modified through full solution treatment and subsequent cold working and aging at carbide precipitation temperature and then heating to recrystallization at temperatures of the levels low enough so that no carbide redissolution takes place.
In contrast to the traditional mill annealing process, the thermomechanically treated material showed satisfactory immunity to intergranular corrosion. A typical structure obtained by this process is associated with fine crystal grain size and evenly dispersed fine spherical M23C6 type carbide particles.
In addition to such resistance the material showed improved tensile properties due to the Hall-Petch effect with the refined grain size and the fine carbide dispersion.

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Effect of Nickel on the Toughness of Type 13Cr-Ni Cast Steel

Yoshitaka IWABUCHI

pp. 120-127

抄録

A study has been made of the effect of Ni content on the toughness of low C-13Cr martensitic stainless cast steels containing 4 to 6 percent Ni.
The main results are as follows:
(1) The superior toughness is obtained in a specimen tempered at temperature around 600°C.
(2) Upper shelf energy is a function of the strength, and decreased with increasing Ni content.
(3) Impact energy in the transition range is determined by the both of strength and reverted austenite content depending on Ni content.
(4) Increase of Ni deteriorates the toughness as the results of grain boundary embrittlement due to slow cooling from tempering temperature.

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On-line Analyzer for Ni-Zn Alloy Electroplated Film on Steel

Nobukatsu FUJINO, Yoshiro MATSUMOTO, Atsuyoshi SHIBUYA, Hideyoku NAKAHARA, Ikuo NAKASE, Akihiro KOTZUMI

pp. 128-135

抄録

The Ni-Zn electroplated steel sheet shows good corrosion resistance. On producing this sheet it is important to control the coating weight and the Ni content of alloy film for quality assurance. On line X-ray fluorescence analyzer has been developed for the determination of the coating weight and the Ni content of alloy film.
The main features of the instrument are as follows:
(1) Analysis can be done full automatically. (2) The X-ray fluorescence method is used. In the analysis system, X-ray intensities are measured by two detectors (ionization chambers), one is with Fe filter and the other with Ni filter. The coating weight and the Ni content are calculated from the intensities measured by the two detectors. (3) This analyzer is running for about two years without any trouble.

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特殊鋼の連鋳比率の現状/航空機用ジェットエンジンの構成材料の推移及び予測/「最適化」を巡つて

木原 諄二

pp. 144-144

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武田 幹治, 児玉 琢磨, 高島 暢宏, 重松 石削, 八木 晃一, 新谷 紀雄

pp. 145-146,144

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