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鉄と鋼
Vol. 58 (1972), No. 1

鉄と鋼 Vol. 58 (1972), No. 1

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オンライン版ISSN:	1883-2954
冊子版ISSN:	0021-1575
発行機関:	The Iron and Steel Institute of Japan

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キーワードランキング

03 Dec. (Last 30 Days)

鉄と鋼 Vol. 58 (1972), No. 1

1971 Perspective of Production and Technique of Iron and Steel in Japan

Tsuneyo IKI

pp. 3-17

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Thermodynamic Conditions of MgO and MgO∙Al₂O₃ Formation and Variation of Inclusions Formed in Fe-17mass%Cr Steel at 1873 K

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Prediction of Blast Pressure Change by a Mathematical Model

Naochika MIYASAKA, Masayasu SUGATA, Yukiaki HARA, Shin-ichi KONDO

pp. 18-28

抄録

Simulation of a blast furnace by a mathematical model is one of the means, by which the phenomena in the blast furnace, especially in the high temperature zone, are quantitatively understood. The means described are as follows;taking account of the dead man, the blast furnace from top of bed to tuyere level is devided into five parts, i. e., indirect reduction zone, smelting zone, direct reduction zone, tuyere zone and race-way zone. In each zone the twelve simultaneous ordinary differential equations, consisting of the heat transfer and reaction rate equations, are set up. Rate equations of six kind of chemical reactions and the equations concerning the flow of fluids, which are expected to occur in the blast furnace, have been obtained experimentally. Furthermore, a few parameters are determined, so as the computed curves of pressure drop and temperature to agree with those measured in a actual large blast furnace.
In a actual furnace, it occurs sometimes that the blast pressure increases abnor mally, and then the state of the furnace becomes worse and finally serious. As the results of analysing such case by the use of the mathematical model, the increase of the blast pressure can be predicted before about three hours.

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Kinetics of Decarburization of Liquid Iron at Low Concentrations of Carbon

Hiroyuki NOMURA, Kazumi MORI

pp. 29-40

抄録

The present paper deals with a kinetic study of decarburization of liquid Fe-Ca lloy in CO-CO₂ atmospheres at 1 600°C. The study has been especially directed towards determining the rate-controlling steps at low carbon contents of the melt.
In the concentration range above 0.05%C, the rate of decarburization is influenced by the gas flow rate.
It is shown that at carbon content higher than 0.1-0.15%, the decarburization controlled by gaseous diffusion.
In the concentration range below 0.05%C, the rate of decarburization no longer depends on the gas flow rate, if it is higher than 1 300cc/min. The views on the mechanism of decarburization under this condition are summarized as follows;
(1) The decarburization by blowing gas of the ratio pco, /pco below 1/4 is controlled by chemical reaction.
The rcactions conceived here are;C+CO₂k₁→k_1′2CO₃, CO₂k₂→k_2′CO+O, C+Ok₃→k_3′The results can be explained reasonably well by postulating appropriate values for k₂, k_3′, k_1′/_k3′.
(2) At higher gas ratio (Pco₂/Pco≥1/4), the rate-determining factor changes gradually.It is shown that at pco₂, /pco≥7/3, the decarburization is controlled by the mass transfer of carbon in liquid iron, themass transfer coefficient being 0.036cm/sec.

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Effect of Sulfur on Solidification of Rimming Steel

Masayoshi KUBA, Ko TASAKA, Yukiyoshi ITOH, Hirobumi MAEDE

pp. 41-59

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With intent to make clear the effect of sulfur on the solidification of rimming steel, the properties of low sulfur rimming steel ingots were examined and were compared with that of standard rimming steel ingots.The characteristics of low sulfur rimming steel ingots were summarized as follows:
(1) The number of the elongated blowholes diminishs and the thick solid-skins develope, but some skin holes are formed.
(2) Plenty of MnO (FeO) inclusions are precipitated on the inner surface of blowholes.
(3) Carbon contents of ingots are low in comparision with that of liquid steel in ladle.Sulfur contents of ingots are very low as was expected, but the segregation ratios are rather high.
(4) Sulfide inclusions decrease and oxide inclusions slightly increase, while gross inclusions exceedingly decrease.
These characteristics of low sulfur rimming steel ingots are attributed to the C-O reaction, the fluid motion and the surface tention of liquid steel in mold.

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On the Morphology of Non-metallic Inclusions and the Machinability of Calcium Deoxidized Steel

鉄と鋼 Vol.57(1971), No.13

Non-Metallic Inclusions in Calcium-Aluminum Complex Deoxidized Steel

鉄と鋼 Vol.57(1971), No.13

A Model Experiment on Relationship between Fatigue Properties of Steel and Size, Shape, and Distribution of Inclusions

鉄と鋼 Vol.57(1971), No.2

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The Behavior of Oxide Inclusions in the Solidification Process of Steel ingot

Koreaki SUZUKI, Masaru FUKUMOTO, KOZO TANIGUCHI

pp. 60-75

抄録

It was found that a large number of inclusions with various sizes were suspended in a molten steel taken from a tapping ladle and the number of fine inclusions did not decrease by killing for about 20 min. The chemical composition and the number of these inclusions were determined.The distribution of inclusions in the bottom half of 7 ton ingots was inverstigated, taking above results into consideration. In particular, diffusion growth mechanism was applied theoretically for the growth of inclusion in the negative segregated zone of these ingots.
Observation of macroscopic inclusions, which appeared in the negative segregated zone of a 90 ton ingot, indicated that the formation of the inclusions was closely related to the solidification condition in the region.

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On the Reactions between Non-metallic Inclusion and Matrix Metal in a Rimmed Steel

鉄と鋼 Vol.57(1971), No.1

Deoxidation and Desulfurization of Liquid Steel with Calcium Complex Alloys

鉄と鋼 Vol.57(1971), No.12

On the Relationship between Machinability and Inclusion Morphology of Ca Bearing Free Machining Steels

鉄と鋼 Vol.57(1971), No.13

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A Model Study on Jet Penetration and Slopping in the LD Converter

Hidetake ISHIKAWA, Shozo MIZOGUCHI, Kiyoshi SEGAWA

pp. 76-84

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A simulation study was made of the jet penetration and the splashing of molten materials due to oxygen jet (slopping or spitting) in the LD converter.
By investigating the relations among the blowing conditions, the penetration depth and the splashing height, empirical formulas for these relations that are applicable to large scale apparatus were derived.
From the results of this study, an equation for estimating the penetration depth in the actual LD furnace and some knowledges useful for realizing the physical characteristics of slopping and spitting were obtained.

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Effect of Small Additions of Ti and Nb on the Creep-Rupture Strength of High-Alloy Austenitic Stainless Steels

鉄と鋼 Vol.57(1971), No.1

High Temperature Deformation Behavior of SKD11 Die Steel

鉄と鋼 Vol.79(1993), No.6

Progress on the Rolling Technics-Tube Manufacturing

鉄と鋼 Vol.59(1973), No.13

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Shape Factor of Calibers in Rolling of Structural Sections

Hiroyuki HIRAMATSU

pp. 85-92

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A new equivalent rectangle method has been developed and the factor depending on shape of sections has been determined in caliber rolling of structural sections. To confirm the correctness of this method, the calculated results of ratio of torque/force in various calibers have been compared with those obtained from measurements of roll force and power. It may be applied with sufficient accuracy for calculation of roll force and power. For a condition of the practical hot rolling, the following values appear to give the best results: average coefficient of friction μ=0.15, average angle of friction cosφ=0.65, efficiency of deformation η=0.35, average lever arm ratio λ₀=0.37.

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Industrial Instrument Standard in the Iron and Steel Industries

鉄と鋼 Vol.57(1971), No.12

On the Dissolution Process of Deoxidizer into Molten Iron and the Mechanism of Formation of Oxide Inclusions

鉄と鋼 Vol.57(1971), No.13

Oo Structural Diagram of Austenitic 25%Cr-20%Ni-Fe-C Type Alloys

鉄と鋼 Vol.58(1972), No.1

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Effects of Carbon Content on Primary Recrystallization Texture in Fe-Al-N Alloys

Tadashi ICHIYAMA, Ikushi YOSHIDA, Mizuo EJIMA, Osamu MATSUMURA

pp. 93-106

抄録

Fe-Al-N alloys investigated contained<0.005%, -0.06% Al, <0.002%-0.02% N and 0.001%-0.04%C. Effects of C content on primary recrystallization texture, A1N precipitation, grain size and drawability in these alloys were studied.
With increasing C content, the amount of grains with {111} lattice plane parallel to the sheet plane decreases, the main component of primary recrystallization texture changes from {111}‹110› to {554}‹225›, grain size decreases, grain shape changes from the “pancake” to the equiaxial type, and thedrawability markedly decreases.
These effects of C content on various properties of Fe-Al-N alloys are rather inconspicuous for the C content up to 0.01%but become extremely remarkable when it exceeds 0.01%and are explained by the effect of C content on AIN precipitation during precipitation treatment prior to cold rolling and during heating to (and at) the annealing temperature.

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Oo Structural Diagram of Austenitic 25%Cr-20%Ni-Fe-C Type Alloys

Kazuyoshi NISHINO, Naohiko KAGAWA

pp. 107-118

抄録

To establish the structural diagram of 25%Cr-20%Ni-Fe-Calloys in which carbon content is lower than2.4wt%, were studied thermal characteristics such as melting temperature, carbide solubility in austenitic phase, and stability of carbides and sigma phase. In addition to the sectional diagram shown in Fig. 16 in the text, the remarkable results are as follows.
(1) The solubility of M₂₃C₆type carbide in austentitc phase is shown by where C is the carbon content (wt%) in solid solution and T the absolute temperature
(2) Sigma phase precipitates within austenite phase in the alloys of lower carbon content. On the other hand, in the case above about 0.25%C, it is likely that M₂₃C₆type carbide transforms to sigma phase.

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Effect of Small Additions of Ti and Nb on the Creep-Rupture Strength of High-Alloy Austenitic Stainless Steels

鉄と鋼 Vol.57(1971), No.1

Precipitation Control of Cold Rolled Mild Steel Sheets in Thin Slab-Direct Hot Rolling Processes

鉄と鋼 Vol.79(1993), No.2

The Development of Rolling Technique on Bar and Rod

鉄と鋼 Vol.59(1973), No.13

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Effect of Ni on the Behavior of Austenite Grain in Ni-Cr-Mo-V Steels

Ryosuke HONMA

pp. 119-127

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In relation to the fact that Ni-Cr-Mo-V Steels containing 3 to 4%Ni have a tendency to form coarse austenite grains, an investigation was made on the effect of Ni on the behavior of austenite grains in this kind of steel.
Four materials of a fixed chemical composition except for Ni content which was varied in the range from 0 to 4.5%were prepared. Specimens which have martensitic structure obtained by preliminary quenching from 1250°C were heated to 900°C. Austenite grain size at 900°C and structural changes during heating in these specimens were observed.
It was found that austenitie grain size tend to become coarser with increase in Ni content. Further, it was known that acicular austenite grains which were formed in early stage of austenitization became finer and more stable with increase in Ni content.
Based on these results, considerations were made on the austenitizing mechanism of steels which have acicular prior structure.
It seems reasonable to consider that coarse equiaxed austenite grains are formed as a result of preferential growth of a small number of acicular austenite grains.
It is believed that the role of Ni in formation of coarse austenite grain in Ni-Cr-Mo-V steels is to make the lattice orientation of acicular austenite grains uniform, and, consequently to increase the stabilization of acicular grains, this being a necessary condition for preferential growth of a small number of these grains.

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なんとかしてもらいたい三つの問題

鉄と鋼 Vol.64(1978), No.5

Nucleation Sites of Austenite from Lath Martensite in Fe-0.2%C-X Alloys

鉄と鋼 Vol.64(1978), No.5

Reverse Transformation of Low-carbon Low Alloy Steels

鉄と鋼 Vol.60(1974), No.2

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Studies of6%Nickel Steel for Low Temperature Use

Shin'ichi NAGASHIMA, Takayuki OOKA, Shozo SEKINO, Hiroshi MIMURA, Toshiyuki FUJISHIMA, Seinosuke YANO, Hiroshi SAKURAI

pp. 128-141

抄録

Studies were made in connection with the development of a new steel for low-temperature use.The ef-fects of alloying elements on the toughness of6%Ni steel were examined in relation to metallurgical factors such as temper brittleness, microstructure and the stability of temper-formed austenite (reverted austenite). The results are as follows:(1) The addition of manganese refines the microstructure and improves toughness but promotes susceptibility to temper brittleness.(2) The addition of molybdenum or tungsten is bene ficial in preventing temper brittleness of6%Ni steel with a high manganese content and in producing finely dispersed and stable austenite islands, but has the disadvantage of retarding recovery on tempering.(3) The addition of chromium is useless in improving the toughness of 6% steel.(4) The addition ofcopper has similar effects to those of manganese, that is, it refines the microstructure and improves toughness.
Based on these results, a new steel has been developed with 6%Ni, 1-2%Mn and 0.2%Mo or 0.45%W, which has good toughness, such as 13kgm at-196°C.

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Industrial Instrument Standard in the Iron and Steel Industries

鉄と鋼 Vol.57(1971), No.12

Shape Factor of Calibers in Rolling of Structural Sections

鉄と鋼 Vol.58(1972), No.1

On the Dissolution Process of Deoxidizer into Molten Iron and the Mechanism of Formation of Oxide Inclusions

鉄と鋼 Vol.57(1971), No.13

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The Determination of Boron Nitride in Steel by Means of Infrared Spetrometry

Kimio SUGIMOTO, Masary YAMAGUCHI, Haruhisa IWAKIRI, Hiroshi HARA

pp. 142-150

抄録

A rapid and sensitive infrared spectrometric method is described for the determination of microgram quantities of boron nitride in steel. An infrared absorption spectrum of boron nitride (BN) is characteristic and sensitive as reported by Ohiko Kammori and others, by whom a very successful method for the determination of BN in steel has been proposed.
In this study further improvements were made by employing the procedure of the incineration of the residues, that is, the recovery of BN on filter became complete and very little effects of other chemical compounds (carbides, filter, etc.) were observed.
0.5 to 1.0g of sample is dissolved with 50ml of H₂SO₄ (1+6) in a 200ml beaker, then the solution is filtered with fine pore size filter as used for BaSO₄ filtration. The residues on filter paper in a crucible is heated very gently with small flame of burner until all the paper is reduced to carbon without taking fire, then incinerated in electric furnace at 500°C for 20 minutes.The resulting residues mixed with 300 mg of KBr for about 15 minutes in agate motor is prepared into a pellet of 13 mm in diameter. Absorbance measurements of the characteristic BN band at 1380-1 cm are made by the base line method. The minimum detectable content of BN in steel was 0.0001% and the calculated values as B agreed to the acid insoluble B content.

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End Point Temperature Control of Basic Oxygen Converter by Sub-lance

Seiki TSUZUKI, Katsuaki KOKAI, Toru FURUSAKI, Toshio TAKAHASHI

pp. 151-157

抄録

A new end point temperature control system introducing a sublance has been developed in Steelmaking Plant-II (nominal capacity: 100t×2, 110t×1), Muroran Works, Nippon Steel.
The main body of the sub-lance is a water-cooled steel pipe (2-1/2, O. D.) which moves up and down vertically along the guide rail. The sensor attached to the tip of the lance is a consumable immersion thermo-couple of the same type as that used in the turn-down temperature measurement.
By using the sub-lance, the bath temperature can be measured without stopping the oxygen blow, and “dynamic end point control” has thus become possible. Of every heat, the sub-lance starts to measure the bath temperature at 350 Nm³ (one minute) prior to the calculated total oxygen, and the rising temperature curve is modified accordingly.
Since September 1968, when it was made operative at No3 vessel, the sub-lance has been working quite satisfactorily.
As the result:
(1) The end point temperature control (±10°C) was improved by 15-17% reaching 87% of the on-temperture rate.
(2) Consequently efficiency in steelmaking was improved markedly, and in April 1970 the plant established a world record of 2 762 heats per month.

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Petrographic Studies and Its Utilization of Coal for Coke Making

Hideo KIMURA, Takashi MIYAZU

pp. 158-179

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Testing Method of Vanadium Pentoxide Attack of Steels

Ohmi MIYAGAWA

pp. 180-201

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On the Universal Decimal Classification Explanation of the UDC

Yoshihiko YAMAMURA

pp. 202-207

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pp. 208-216

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03 Dec. (Last 30 Days)

In-situ Observation of Precipitation and Growth of MnS Inclusions during Solidification of a High Sulfur Steel

ISIJ International 早期公開
Measurement of Bubble Size Distribution and Generation Position of Bubbles Generated during Smelting Reduction of Iron Oxide-containing Slag

ISIJ International 早期公開
Injection of hydrogenous gases into the blast furnace tuyeres for reducing CO₂ emissions: a review

ISIJ International 早期公開
凝固過程における溶鋼中からAl₂O₃上へのMnSの晶出挙動

鉄と鋼早期公開
Fe–(0.5–2.0)%Al–2.0%Mn合金の一方向凝固におけるAlNの晶出挙動に及ぼすAl濃度の影響

鉄と鋼早期公開
Molecular dynamics simulation of viscosity of the CaO, MgO and Al₂O₃ melts

ISIJ International 早期公開
One-Pot Sonochemical Synthesis of Carbon Nano-Onions from Silicon Carbide in Pure Water

MATERIALS TRANSACTIONS Vol.65(2024), No.11
Terminal Settling Velocity of Particle in Suspension

ISIJ International 早期公開
Reduction and Carburization Behaviors of Iron Oxide Composite with Iron Carbide and Free Carbon

ISIJ International 早期公開
Development of a Low-carbon Sintering Process Technology and Its Application to a Pilot-scale Sintering Testing

ISIJ International Vol.64(2024), No.13

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鉄と鋼 Vol. 58 (1972), No. 1

キーワードランキング

kinetics of decarburization of liquid iron with high concentration ofcarbon

gasification

kinetics of decarburization of liquid iron by ar-coz gasmixture

19al6mg

automotive wheel

charpy impact chemistry

evaluation of wettability at interface between molten slag and liquid fe on recovery of metallic fe from lunar regolith

kinetics of decarburization of liquid iron by

reduction caco3 in electric furnace

scm440

鉄と鋼 Vol. 58 (1972), No. 1

1971 Perspective of Production and Technique of Iron and Steel in Japan

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Prediction of Blast Pressure Change by a Mathematical Model

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Kinetics of Decarburization of Liquid Iron at Low Concentrations of Carbon

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Effect of Sulfur on Solidification of Rimming Steel

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The Behavior of Oxide Inclusions in the Solidification Process of Steel ingot

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A Model Study on Jet Penetration and Slopping in the LD Converter

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Shape Factor of Calibers in Rolling of Structural Sections

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Effects of Carbon Content on Primary Recrystallization Texture in Fe-Al-N Alloys

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Oo Structural Diagram of Austenitic 25%Cr-20%Ni-Fe-C Type Alloys

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Effect of Ni on the Behavior of Austenite Grain in Ni-Cr-Mo-V Steels

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Studies of6%Nickel Steel for Low Temperature Use

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The Determination of Boron Nitride in Steel by Means of Infrared Spetrometry

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End Point Temperature Control of Basic Oxygen Converter by Sub-lance

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Petrographic Studies and Its Utilization of Coal for Coke Making

SNSによる共有

Testing Method of Vanadium Pentoxide Attack of Steels

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On the Universal Decimal Classification Explanation of the UDC

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抄録

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論文アクセスランキング

In-situ Observation of Precipitation and Growth of MnS Inclusions during Solidification of a High Sulfur Steel

Measurement of Bubble Size Distribution and Generation Position of Bubbles Generated during Smelting Reduction of Iron Oxide-containing Slag

Injection of hydrogenous gases into the blast furnace tuyeres for reducing CO2 emissions: a review

凝固過程における溶鋼中からAl2O3上へのMnSの晶出挙動

Fe–(0.5–2.0)%Al–2.0%Mn合金の一方向凝固におけるAlNの晶出挙動に及ぼすAl濃度の影響

Molecular dynamics simulation of viscosity of the CaO, MgO and Al2O3 melts

One-Pot Sonochemical Synthesis of Carbon Nano-Onions from Silicon Carbide in Pure Water

Terminal Settling Velocity of Particle in Suspension

Reduction and Carburization Behaviors of Iron Oxide Composite with Iron Carbide and Free Carbon

Development of a Low-carbon Sintering Process Technology and Its Application to a Pilot-scale Sintering Testing

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Injection of hydrogenous gases into the blast furnace tuyeres for reducing CO₂ emissions: a review

凝固過程における溶鋼中からAl₂O₃上へのMnSの晶出挙動

Molecular dynamics simulation of viscosity of the CaO, MgO and Al₂O₃ melts