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鉄と鋼
Vol. 53 (1967), No. 12

鉄と鋼 Vol. 53 (1967), No. 12

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オンライン版ISSN:	1883-2954
冊子版ISSN:	0021-1575
発行機関:	The Iron and Steel Institute of Japan

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キーワードランキング

21 Nov. (Last 30 Days)

鉄と鋼 Vol. 53 (1967), No. 12

随想

吉田浩

pp. 1379-1380

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Thermodynamics of Liquid Iron Solutions

Dr. L. S. DARKEN

pp. 1381-1392

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Prediction of the Thermodynamic Properties and Phase Diagrams of Silicate Systems–Evaluation of the FeO-MgO-SiO₂ System

ISIJ International Vol.33(1993), No.1

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On the Rate of Absorption of Nitrogen in Liquid Iron and Iron Alloys, Containing Carbon, Silicon, Manganese and Chromium

Takao CHOH, Michio INOUYE

pp. 1393-1406

抄録

The rates of absorption of nitrogen in liquid iron and liquid iron alloys were measured for inductively melted iron under pure nitrogen at 1600°C.
The experimental data show a linear correlation, which gives the apparent mass transfer coefficient, k′, when the variable, log [(Cs-Co)/(Cs-C)] is plotted vs F·t/V.
The experimental values of the apparent mass transfer coefficient obtained for lower oxygen melts are as follows:
k′=34-35×10^-3 cm·sec^-1 for 0.005-0.006% O
k′=27-29×10^-3cm·sec^-1 for 0.008-0.013% O
At present, it appears that the transfer of nitrogen across the gas/metal interface is controlled by the transport in the metal. Some models of gas absorption in liquid, such as the film theory, the penetration theory and the surface renewal theory, were taken into account to explain the present results.
The effects of several alloying elements on the absorption rates were also measured. It is to be noted that carbon, chromium and manganese have practically little influence, silicon, however, has somewhat remarkable influence in the lower concentrations. Namely, mass transfer coefficient increases gradually as silicon increases and reaches the limiting value of 5×10^-2 cm·sec^-1 at about 2% Si. It seems reasonable to consider that silicon reduces oxygen poison effect which is caused by absorption of dissolved oxygen on the metal surface, even in low oxygen level (0.002% O).
Transfer of nitrogen from gas into liquid iron may also be chemically controlled when the liquid iron contains some surface active agents. The role of surface active agents such as oxygen and sulphur will be discussed in the next paper.

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Several Phenomena Taking Place in Remaining Molten Steel in Large Killed Steel Ingots during Solidification Process

Yoshitaka NAKAGAWA, Akitsugu MOMOSE

pp. 1406-1424

抄録

Several phenomena which take place in remaining molten steel in large killed steel ingots during solidification process have a great influence on those internal guality. Thus, it is essential in making sound steel ingots, to bring light on this problem.
In this report, floatation of segregated molten steel and settling phenomenon of crystals was studied to which especial importance have been attached among those phenomena.
The obtained results are as follows:
i) During the solidification process of steel ingots, the comparatively fast movement of solutes in remaining molten steel is behaved, and the concentration gradient toward the top is formed in it.
Such a phenomenon cannot be explained unless it is supposed that the segregated molten steel moves with some mass.
As a mechanism of floatation, various things are thought. According to the result of authors' model experiment; it was shown that the floatation of segregated molten steel is acted even in static steel bath at velocity or the order of 10^-2-10^-1cm/sec which is able to explain various phenomena taking place in practical steel ingots.
ii) It is assumed that the inertia flowing of molten steel taking place in pouring process has a great influence on the movement of solutes in remaining molten steel at the beginning of solidification process.
iii) The theory that natural convection (thermal convection and solute convection) will take place in remaining molten steel during solidification process has been strongly supported. But it is still unknown how far it will mainly act.
iv) So far the theory (gravity theory and convection one) that crystal particles are formed in remaining molten steel during solidification process, and that they settle down to form the negative segregation zone (settling crystal zone) is strongly supported. However according to the results of authors' experiments, such a conclusion was obtained that this theory has many problems, and it is rather unreasonable to explain various phenomena taking place during solidification process.

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Dislocation Theory of Strength of Iron and Steel

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21 Nov. (Last 30 Days)

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鉄と鋼 Vol. 53 (1967), No. 12

キーワードランキング

reduction caco3 in electric furnace

kinetics of decarburization of liquid iron with high concentration ofcarbon

kinetics of decarburization of liquid iron by ar-coz gasmixture

ahss

charpy impact chemistry

dual phase steel

foamy slag in eaf

kinetics of decarburization of liquid iron by

ladle furnace flicker

scm440

鉄と鋼 Vol. 53 (1967), No. 12

随想

SNSによる共有

Thermodynamics of Liquid Iron Solutions

SNSによる共有

On the Rate of Absorption of Nitrogen in Liquid Iron and Iron Alloys, Containing Carbon, Silicon, Manganese and Chromium

SNSによる共有

Several Phenomena Taking Place in Remaining Molten Steel in Large Killed Steel Ingots during Solidification Process

SNSによる共有

Theory of Solidification and Segregation

SNSによる共有

Dislocation Theory of Strength of Iron and Steel

SNSによる共有

抄録

SNSによる共有

論文アクセスランキング

In-situ Observation of Precipitation and Growth of MnS Inclusions during Solidification of a High Sulfur Steel

Measurement of Bubble Size Distribution and Generation Position of Bubbles Generated during Smelting Reduction of Iron Oxide-containing Slag

Injection of hydrogenous gases into the blast furnace tuyeres for reducing CO₂ emissions: a review

Development of a Low-carbon Sintering Process Technology and Its Application to a Pilot-scale Sintering Testing

凝固過程における溶鋼中からAl₂O₃上へのMnSの晶出挙動

Molecular dynamics simulation of viscosity of the CaO, MgO and Al₂O₃ melts

Fe–(0.5–2.0)%Al–2.0%Mn合金の一方向凝固におけるAlNの晶出挙動に及ぼすAl濃度の影響

凝固過程のミクロ偏析による溶質濃度分布の定量的理解

SOKD: A soft optimization knowledge distillation scheme for surface defects identification of hot-rolled strip

Reduction and Carburization Behaviors of Iron Oxide Composite with Iron Carbide and Free Carbon

詳細検索

鉄と鋼 Vol. 53 (1967), No. 12

キーワードランキング

reduction caco3 in electric furnace

kinetics of decarburization of liquid iron with high concentration ofcarbon

kinetics of decarburization of liquid iron by ar-coz gasmixture

ahss

charpy impact chemistry

dual phase steel

foamy slag in eaf

kinetics of decarburization of liquid iron by

ladle furnace flicker

scm440

鉄と鋼 Vol. 53 (1967), No. 12

随想

SNSによる共有

Thermodynamics of Liquid Iron Solutions

SNSによる共有

On the Rate of Absorption of Nitrogen in Liquid Iron and Iron Alloys, Containing Carbon, Silicon, Manganese and Chromium

SNSによる共有

Several Phenomena Taking Place in Remaining Molten Steel in Large Killed Steel Ingots during Solidification Process

SNSによる共有

Theory of Solidification and Segregation

SNSによる共有

Dislocation Theory of Strength of Iron and Steel

SNSによる共有

抄録

SNSによる共有

論文アクセスランキング

In-situ Observation of Precipitation and Growth of MnS Inclusions during Solidification of a High Sulfur Steel

Measurement of Bubble Size Distribution and Generation Position of Bubbles Generated during Smelting Reduction of Iron Oxide-containing Slag

Injection of hydrogenous gases into the blast furnace tuyeres for reducing CO2 emissions: a review

Development of a Low-carbon Sintering Process Technology and Its Application to a Pilot-scale Sintering Testing

凝固過程における溶鋼中からAl2O3上へのMnSの晶出挙動

Molecular dynamics simulation of viscosity of the CaO, MgO and Al2O3 melts

Fe–(0.5–2.0)%Al–2.0%Mn合金の一方向凝固におけるAlNの晶出挙動に及ぼすAl濃度の影響

凝固過程のミクロ偏析による溶質濃度分布の定量的理解

SOKD: A soft optimization knowledge distillation scheme for surface defects identification of hot-rolled strip

Reduction and Carburization Behaviors of Iron Oxide Composite with Iron Carbide and Free Carbon

詳細検索

Injection of hydrogenous gases into the blast furnace tuyeres for reducing CO₂ emissions: a review

凝固過程における溶鋼中からAl₂O₃上へのMnSの晶出挙動

Molecular dynamics simulation of viscosity of the CaO, MgO and Al₂O₃ melts