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材料と環境 Vol. 70 (2021), No. 5

ISIJ International
belloff
オンライン版ISSN: 1881-9664
冊子版ISSN: 0917-0480
発行機関: Japan Society of Corrosion Engineering

Backnumber

  1. Vol. 73 (2024)

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  2. Vol. 72 (2023)

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  4. Vol. 70 (2021)

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  7. Vol. 67 (2018)

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  9. Vol. 65 (2016)

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  10. Vol. 64 (2015)

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  12. Vol. 62 (2013)

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  18. Vol. 56 (2007)

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  19. Vol. 55 (2006)

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  21. Vol. 53 (2004)

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  22. Vol. 52 (2003)

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  27. Vol. 47 (1998)

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  28. Vol. 46 (1997)

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  29. Vol. 45 (1996)

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  30. Vol. 44 (1995)

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  31. Vol. 43 (1994)

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  32. Vol. 42 (1993)

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  33. Vol. 41 (1992)

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  34. Vol. 40 (1991)

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キーワードランキング

28 Apr. (Last 30 Days)

材料と環境 Vol. 70 (2021), No. 5

硫酸溶液中におけるニオブの電解研磨に対するパルス電位モードの影響

三浦 佑太, 八代 仁, 仁井 啓介, 文珠四郎 秀昭

pp. 145-149

DOI:

10.3323/jcorr.70.145

抄録

The electropolishing behavior of Nb in a 30 wt％ sulfuric acid solution was investigated by controlling the potential of Nb using a three-electrode cell. The Electropolishing was performed with various combinations of cathodic pulse potential （Ec） and anodic one （Ea）. Almost completely mirrored surface was obtained after 120 minutes under the condition of Ec＝－3.0 V and Ea＝＋10 V with both pulse periods of 2.0 ms. The mirrored surface was also obtained within 60 minutes by shortening anodic pulse time （ta） to 1.0 ms at Ec＝－3.0 V and Ea＝＋10 V. This is due to the fact that anodic current decays so quickly at Ea＝＋10 V that anodic pulse time can be shortened to 0.25 ms with no change in anodic charge in one pulse. Thus the total number of cycles in a given time can be increased by shortening ta, which leads to faster electropolising rate: 0.92μm min－1 at ta＝2.0 ms and 1.52μm min－1 at ta＝0.25 ms.

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硫酸溶液中におけるニオブの電解研磨に対するパルス電位モードの影響

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湿潤面用塗料の塗膜形成過程の解析

志村 邦夫, 太田 優輝, 柳口 剛男, 松田 英樹

pp. 150-154

DOI:

10.3323/jcorr.70.150

抄録

The electrochemical impedance spectroscopy （EIS） was examined as the method for analyzing the film formation of an amine cured epoxy paint applied in a wet surface. The impedance characteristics of the models with the epoxy resin and amine curing agent which different affinity for water were analyzed. It was found that the hydrophobic paint film was less affected by the wet environment than the hydrophilic paint film, and the resistance develops in a short time. In addition, from the results of adhesive strength, it was estimated that the water film at the substrate/coating film interface was eliminated in the very early stage. The EIS method was found to be useful for analyzing the coating film formation process in a wet surface.

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湿潤面用塗料の塗膜形成過程の解析

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不飽和ポリエステルをマトリクスとしたGFRPの弱アルカリ水溶液中での劣化特性

竹内 陽祐, 伊藤 陽, 笠原 久稔, 岡村 陽介, 玉松 潤一郎

pp. 155-160

DOI:

10.3323/jcorr.70.155

抄録

In order to verify the applicability of glass-fiber reinforced plastics with an unsaturated polyester matrix in manhole environments, degradation characteristics in a weak alkaline aqueous solution were evaluated based on solution immersion test. The decrease in flexural strength after immersion test at 313 K fitted well to the logarithmic approximation. Based on Arrhenius equation, we estimated the deterioration behavior under 288 K conditions, which corresponded to a manhole environment. However, since a problem in applying the logarithmic approximation became clear, a more appropriate estimation method is required.

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不飽和ポリエステルをマトリクスとしたGFRPの弱アルカリ水溶液中での劣化特性

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連続定電流ステップ法による各種ステンレス鋼のすきま腐食進展性評価

松橋 亮, 野瀬 清美, 松岡 和巳, 梶村 治彦

pp. 161-169

DOI:

10.3323/jcorr.70.161

抄録

The new evaluation test method, CCS （Continuous Current Step） method, for crevice corrosion propagation of stainless steels was proposed. This CCS method is based on the crevice corrosion propagation mechanism of stainless steels in natural seawater. The steady state potential （EOUT） is measured galvanostatically on CCS test. The data sets of EOUT－i were obtained for various stainless steels. It was considered that this EOUT reflected the state of active corrosion in anolyte of inside crevice under the constant current density.The EOUT－i data was analyzed by the exponential decay curve. When the current density i was under 1× 10－5 A cm－2（ ≈0.1 mm/y）, the obtained potential EOUT was considered as the repassivation potential called ER（CCS） in this test. The crevice corrosion propagation was regarded as stop at less noble potential of ER（CCS）.The effects of Cr, Ni, Mo and Cu on the EOUT－i relations were tested in artificial seawater. ER（CCS） related to the metal composition and was described as one equation by using the new index, CCR（Crevice Corrosion Propagation Resistance Index）.CCR＝[Cr]＋0.95[Ni]＋0.74[Mo]＋2.03[Cu]ER（CCS）＝－317＋13.75 CCR（mV vs.SHE）This new index, CCR, succeeded in unification of the crevice corrosion propagation （ER（CCS）） for various stainless steels.

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連続定電流ステップ法による各種ステンレス鋼のすきま腐食進展性評価

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合金化溶融亜鉛めっき鋼板の亜鉛―鉄合金相および鉄―亜鉛固溶相の防食性評価

小成 佳史, 河野 研二, 池田 貢基, 牛 立斌

pp. 170-176

DOI:

10.3323/jcorr.70.170

抄録

The corrosion resistance of the δ1 phase （Zn-Fe compound） coated on galvannealed steel sheets （GA） and the Γ phase （Zn-Fe compound）, α solid solution （Fe-Zn solid solution）, which were formed by heating GA, was investigated using combined cyclic corrosion test, polarization measurements and structure analyses. The results suggest that the α solid solution, Γ and δ1 phases have relatively good corrosion resistance in order, and these coating phases have sacrificial corrosion protection against base steel. It was also considered that the corrosion prevention of α solid solution will decrease when the exposed area of the base steel becomes large.

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合金化溶融亜鉛めっき鋼板の亜鉛―鉄合金相および鉄―亜鉛固溶相の防食性評価

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