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MATERIALS TRANSACTIONS Vol. 63 (2022), No. 9

ISIJ International
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ONLINE ISSN: 1347-5320
PRINT ISSN: 1345-9678
Publisher: The Japan Institute of Metals and Materials

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MATERIALS TRANSACTIONS Vol. 63 (2022), No. 9

Formation and Dispersion of Precipitates during Hot Deformation in Al–1%Mn Alloys

Hiroki Tanaka, Katsuhiro Sasaki, Shinji Tateyama

pp. 1205-1210

DOI:

10.2320/matertrans.MT-L2022012

Abstract

In this study, precipitation behavior in hot workings on Al–1%Mn alloy was investigated. It has been identified specimens used in this study show thermally stabilized substructures after plain strain compression (PSC) test as a hot working. PSC tests were carried out between 300°C and 500°C. By using small angle x-ray scattering (SAXS) method, dispersion state of precipitations formed in hot workings were estimated. It was considered minute precipitations less than 10 nm in diameter were formed in hot worked areas. These minute precipitations were increased with increasing in compression temperature. In invariant area heated at 400°C, precipitations less than 10 nm were not identified. By using of HAADF-STEM, these minute precipitations less than 10 nm were confirmed, and it was cleared due to EDS analysis the precipitations consist of four elements such as aluminum, manganese, iron and silicon. This Paper was Originally Published in Japanese in J. JILM 71 (2021) 549–554. The caption of Fig. 6 is slightly modified.

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Formation and Dispersion of Precipitates during Hot Deformation in Al–1%Mn Alloys

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Investigation of Nanoscale Phase Formation in Rapidly Solidified Fe20Co20Ni20Cr20B20−xSix Alloys

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DOI:

10.2320/matertrans.MT-M2022058

Abstract

In this study, nanoscale phase formation in rapidly solidified Fe20Co20Ni20Cr20B20−xSix alloys was investigated using atom probe tomography (APT) and transmission electron microscopy (TEM). According to previous X-ray diffraction measurements and scanning electron microscopy with energy-dispersive X-ray spectroscopy results, it was thought that this alloy system was composed of almost a single face-centered cubic (FCC) solid solution phase when the Si content was 5 at.%. However, APT and TEM results at the nanoscale showed that both an FCC solid solution and compound phases formed for all alloy compositions. The rapidly solidified alloy ribbon with a Si content of 5 at.% showed the presence of nanoscale FCC and Cr2B phases. Furthermore, in addition to the nanoscale FCC and Cr2B phases, a nanoscale Cr3Ni5Si2 phase was observed when the Si content exceeded 7.5 at.%.

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Analysis of Concentration Dependence of Interdiffusion Coefficient under the Condition of a Time-Varying Surface Concentration

O. Olaye, O. A. Ojo

pp. 1217-1223

DOI:

10.2320/matertrans.MT-M2022029

Abstract

The newly reported forward simulation method is used to extract concentration-dependent interdiffusion coefficient (D=F(C)) from experimental concentration profiles obtained under constant and time-varying surface concentration conditions, which is impossible by the standard analytical methods. Also, theoretical D=F(C) under constant and time-varying surface concentration conditions are computed in systems with diffusion-induced stress generation and relaxation. The experimental and theoretical results show that the long-held general assumption that D=F(C) is the same for constant surface concentration and time-varying surface concentration is not valid, and such assumption can cause model prediction errors in cases where a surface concentration changes with time. These include the use of D=F(C) computed by the standard analytical techniques, such as the Boltzmann-Matano, Sauer-Freise, Hall, and Wagner methods, for predicting diffusion during homogenization processes.

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Analysis of Concentration Dependence of Interdiffusion Coefficient under the Condition of a Time-Varying Surface Concentration

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Synergistic Effect of Different Plastic Deformation Modes: Molecular Dynamics Study on Strength of Crystalline/Amorphous Mixed Systems

Tomotsugu Shimokawa, Kazuki Hara, Tomoaki Niiyama

pp. 1224-1231

DOI:

10.2320/matertrans.MT-Z2022007

Abstract

In order to investigate the synergistic effect of different deformation modes (dislocations and local atomistic rearrangements) on the strength of mixed crystalline and amorphous materials, tensile and compressive deformation analyses of a two-dimensional binary system with various microstructures is performed through molecular dynamics simulations. The binary system is composed of atoms with two different atomic radii. By varying the mixing ratio and the interaction force between different atoms, 66 binary system models with various structures are represented, and each model is classified into three categories, crystalline, amorphous, and mixed crystalline/amorphous, through structural analysis. Deformation analysis shows that the strength of the mixed crystalline/amorphous models tends to be weaker than that of the crystal and amorphous models. The is because the edge of the force chain in the amorphous phase appears at the crystalline/amorphous interface, where dislocation release from the interface to the crystalline phase occurs easily. This Paper was Originally Published in Japanese in J. Soc. Mater. Sci., Japan 71 (2022) 135–142.

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Crack Tip Deformation during Dwell Fatigue and Its Correlation with Crack/Fracture Surface Morphologies in a Bi-Modal Ti–6Al–4V Alloy

Yuma Aoki, Motomichi Koyama, Masaki Tanaka, Kaneaki Tsuzaki

pp. 1232-1241

DOI:

10.2320/matertrans.MT-M2022076

Abstract

We investigated how dwell fatigue loading accelerates the crack propagation in bi-modal Ti–6Al–4V alloy. A fatigue test was programmed to include displacement holding for only one cycle at several ΔK. We found (1) crack tip strain evolved during the displacement holding, (2) the displacement holding increased fatigue striation spacing, and (3) the strain increment during the displacement holding was linearly correlated with spacing of the displacement-holding-extended striations. These facts indicate that the dwell loading assisted crack opening, which accelerated the crack propagation. Other analyses results and discussion are also presented, in terms of crack propagation mode, crack closure, and dislocation structure.

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Crack Tip Deformation during Dwell Fatigue and Its Correlation with Crack/Fracture Surface Morphologies in a Bi-Modal Ti–6Al–4V Alloy

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Improvement of Corrosion Resistance of the AZ91 Magnesium Alloys with Sputtered Aluminum Layer Using Interdiffusion Treatment, Anodic Oxidation Treatment and Sealing Process

Masahiko Hatakeyama, Kenichi Nakano, Ryosuke Yoshita, Daichi Nakato, Satoshi Sunada, Masateru Nose

pp. 1242-1247

DOI:

10.2320/matertrans.MT-MA2022015

Abstract

Magnesium alloys have low corrosion resistance due to their high chemical activity. Therefore, it is necessary to improve their corrosion resistance to use in corrosive environments. In the present study, we aimed to improve the corrosion resistance of AZ91 magnesium alloy in NaCl solution, using aluminum sputtering deposition, anodic oxidation treatment and sealing process were examined. To evaluate the corrosion rate, electrochemical experiments were carried out. In the case of just aluminum sputtering deposition, corrosion resistance was not improved due to small defects in the sputtering deposition. However, corrosion resistance was improved by sputtering deposition followed by interdiffusion treatment at 553 K for more than 3 hours. Corrosion resistance was further improved by anodic oxidation treatment and sealing process after the interdiffusion treatment. With this series of treatments, the corrosion rate of the samples was reduced to 1/360 compared to that of AZ91 base metal. The results show that the interdiffusion treatment, anodic oxidation treatment and sealing process after sputtering deposition are significantly effective to improve corrosion resistance of AZ91 magnesium alloy.

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Improvement of Corrosion Resistance of the AZ91 Magnesium Alloys with Sputtered Aluminum Layer Using Interdiffusion Treatment, Anodic Oxidation Treatment and Sealing Process

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Effect of Large Particles in Central Band of Al–4%Mn–1%Si High-Speed Twin-Roll Cast Strip on Elongation of Cold-Rolled and Annealed Sheets

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DOI:

10.2320/matertrans.MT-L2022003

Abstract

Mn-containing (2 and 4 mass%) Al–Mn-based alloys were fabricated by high-speed twin-roll casting (HSTRC). Al–4 mass%Mn–1 mass%Si strips contained coarse particles in the central band of the cast strips. Microstructure and chemical analyses revealed that the particles were primarily Al6(MnFe) and β-Al(MnFe)Si. These particles formed during the solidification process of the residual liquid, which slowly cooled after the strip exited the roll gap during HSTRC. However, blowing compressed air onto the strip surface as it exited the roll gap rapidly cooled the residual liquid, reducing the number and size of large particles in the central band region. The cold-rolled and annealed sheets fabricated from the strips exhibited a refined and homogenous microstructure. Consequently, both the strength and elongation of the sheets were improved.

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Effect of Large Particles in Central Band of Al–4%Mn–1%Si High-Speed Twin-Roll Cast Strip on Elongation of Cold-Rolled and Annealed Sheets

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Solute Distribution of α-Al Dendrite in Al–Si and Al–Cu Binary Aluminum Alloys during Solidification and Cooling Process

Takuma Minoura, Jun Yaokawa, Hiroaki Iwahori, Yuko Aoki, Mina Iwai, Shuxin Dong, Yasushi Iwata

pp. 1258-1265

DOI:

10.2320/matertrans.F-M2022807

Abstract

To elucidate the segregation behavior of solutes in Al–Si and Al–Cu binary alloys, specimens of several hypo-eutectic Al–Si alloys water-quenched at different stages of solidification or air-cooled from melt to room temperature were prepared and the distributions of Si concentration were analyzed across the primary dendrites. The Si distribution in the dendrites of the specimens water-quenched during primary solidification showed that Si concentration declined from the surface toward the center of the dendrite. In contrast, the specimens water-quenched after eutectic solidification or air-cooled from melt to room temperature showed that Si concentration increased from the surface toward the center of the dendrite. The diffusion distance of Si in the dendrites during the cooling process from the finish of solidification to room temperature was calculated according to Fick’s second law and showed good agreement with the measured value. Therefore, the segregation behavior with high Si concentration in the center of the dendrite was attributed to the diffusion of Si from the center to the surface of the dendrite, resulting in the precipitation on the adjacent Si phase during eutectic solidification. This Paper was Originally Published in Japanese in J. JFS 93 (2021) 169–175. Reference 6) is deleted and the number of References is moved up from then.

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Solute Distribution of α-Al Dendrite in Al–Si and Al–Cu Binary Aluminum Alloys during Solidification and Cooling Process

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Ionic Conductivity of Ca2+ Doped NaI–LiI Solid Electrolyte and Its Stability with Li Metal

Reona Miyazaki, Takamasa Hirai, Takehiko Hihara

pp. 1266-1272

DOI:

10.2320/matertrans.MT-M2022079

Abstract

The effects of Ca2+ doping on the ionic conductivity and the stability with a Li of NaI–LiI solid electrolyte were investigated. Evidence of the Ca2+ doping was found in a Rietveld analysis of the synchrotron X-ray diffraction pattern. The conductivity of 9(9NaI·CaI2)·LiI was measured to be 2 × 10−5 S/cm at 60°C, which was higher than the Ca2+-free sample at the same temperature (1 × 10−5 S/cm). The short-circuit of the Li | 9(9NaI·CaI2)·LiI | Li cell was observed after keeping the cell at the open-circuit. The reductive decomposition of the solid electrolyte to LiI and Ca (or Li–Ca alloy) was suggested by contacting with Li. The short-circuit was attributed to the continuous growth of the Li–Ca alloy. The phase separation at Li/9NaI·LiI interphase was not observed. These results suggest that while Li+ conductors stabilized with Li can be developed based on Na compounds, Ca2+ doping is not an effective strategy to enhance conductivity.

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Ionic Conductivity of Ca2+ Doped NaI–LiI Solid Electrolyte and Its Stability with Li Metal

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Effects of Sulfur and Phosphorus on Binder Decomposition Behavior of Nickel Powder

Seiyu Teruya, Noritaka Saito, Kunihiko Nakashima

pp. 1273-1280

DOI:

10.2320/matertrans.MT-M2021246

Abstract

Fine Ni particles are utilized as internal electrode materials for multilayer ceramic capacitors. Despite extensive research, the effects of the surface properties (additional elements) remain unclear. To the best of our knowledge, the present study is the first to demonstrate the effects of the addition of sulfur (S) and phosphorus (P) on surface modification and binder decomposition during the production of fine Ni particles. Scanning electron microscopy, X-ray diffractometry, thermogravimetry-differential thermal analysis, hydrogen temperature-programmed reduction, temperature-programmed decomposition, and X-ray photoelectron spectroscopy were performed to analyze non-doped Ni, S-doped Ni and P-doped Ni powder. S existed as S–O or Ni–S on the particle surface in the S-doped Ni powder, whereas P existed solely as P–O on the particle surface in the P-doped Ni powder. When formed into a paste with these powders, the decomposition temperature of the binder is lower than that of the binder alone owing to the catalytic effect of the unmodified surface of Ni in non-doped Ni. However, the catalyst poisoning effect of S in S-doped Ni and the coating effect of P–O in P-doped Ni suppressed the lowering of the binder decomposition temperature due to the catalysis of the Ni surface. The results of the present study are expected to inspire future research on the optimization of the manufacturing process of multilayer ceramic capacitors.

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Effects of Sulfur and Phosphorus on Binder Decomposition Behavior of Nickel Powder

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Effect of Binder Chemistry on Dynamic Percolation in Electrically Conductive Carbon-Nanotube-Filled Pastes during Curing

Subaru Tsujimura, Masahiro Inoue

pp. 1281-1286

DOI:

10.2320/matertrans.MT-M2022052

Abstract

The effects of binder chemistry on electrical-conductivity development, i.e., dynamic percolation, in carbon nanotube (CNT)-filled epoxy-based pastes during curing were investigated. The electrical resistivities of the pastes are influenced not only by the dispersivity of the CNT filler but also by the binder chemistry of the pastes. The electrical-conductivity-development kinetics are accelerated by introducing a reactive diluent, namely phenyl glycidyl ether, to the binder. As shown by alternating current impedance spectroscopy, the electrical-conductivity development is governed by the decrease in interfacial electrical resistance between the filler units. Electrical-conductivity development does not occur synchronously with the curing shrinkage of the binder; thus, the chemical state of the interface adjacent to the fillers is a key parameter for enhancing electrical conductivity. Thus, control of this interfacial chemistry is an essential concept for developing electrically conductive CNT-filled pastes.

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Effect of Binder Chemistry on Dynamic Percolation in Electrically Conductive Carbon-Nanotube-Filled Pastes during Curing

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pH Dependance of Scorodite Formation in As(V) Solution Using Magnetite as the Solid Iron Source

Ken Adachi, Takumi Anezaki, Tomoro Karube, Atsushi Iizuka, Etsuro Shibata

pp. 1287-1293

DOI:

10.2320/matertrans.M-M2022806

Abstract

Arsenic-containing wastewater, which is mainly generated in nonferrous metal-smelting plants, threatens the natural environment and human health owing to its high toxicity and mobility. A promising arsenic immobilization method to solve this problem is to immobilize arsenic as scorodite. In this study, the method of scorodite synthesis using magnetite as the iron source was investigated, which can be performed using low-cost materials under atmospheric pressure without using an autoclave. The generation and crystallization behaviors of the intermediate of the gel-like precursor of scorodite were investigated by monitoring the concentration of each iron ion in solution and characterizing the precipitate. By clarifying the effect of the solution pH for each reaction step, the mechanism and suitable conditions of this process are discussed.

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pH Dependance of Scorodite Formation in As(V) Solution Using Magnetite as the Solid Iron Source

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